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[Ni(CN)(4)]^(2-) complex has the shape …...

`[Ni(CN)_(4)]^(2-)` complex has the shape …… and is ….. In terms of magnetic nature whereas `[NiCl_(4)]`^(2-)` has the shape …… and is ….. .

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To solve the question regarding the shapes and magnetic nature of the complexes `[Ni(CN)₄]²⁻` and `[NiCl₄]²⁻`, we will follow these steps: ### Step 1: Determine the oxidation state of Ni in both complexes. - For `[Ni(CN)₄]²⁻`: Let the oxidation state of Ni be \( x \). Since CN is a -1 ligand and there are 4 CN ligands, we have: \[ x + 4(-1) = -2 \implies x - 4 = -2 \implies x = +2 \] - For `[NiCl₄]²⁻`: Similarly, let the oxidation state of Ni be \( y \). Since Cl is also a -1 ligand and there are 4 Cl ligands, we have: ...
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PRADEEP-CORDINATION COMPOUNDS-Fill in the blanks
  1. The formula of sodium hexanitrite cobalt is …… and its IUPAC name is …...

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  2. The formula of sodium nitroprusside is …… and its IUPAC name is ……

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  3. [CoCl(NH(3))(4)(H(2)O)]Br(2) and [Co(NH(3))(4)Br(2)]Cl.H(2)O are …. Is...

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  4. The cis form of the complex [RhCl(3)(py)(3)] is called …… isomer where...

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  5. Two compounds with the formula [Co(NH(3))(4)Cl(2)]^(+)Cl^(-) exist. On...

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  6. Octahedral complexes involving d^(2)sp^(3) hybridisation are called ……...

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  7. [Ni(CN)(4)]^(2-) complex has the shape …… and is ….. In terms of magne...

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  8. In an octahedral crystal field, d - orbitals split into ….. Orbitals c...

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  9. The difference of energy between two sets of d-orbitals obtained due t...

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  10. The arrangement of ligands in order of their crystal field splitting e...

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  11. The average energy level of the perturbed d-orbitals in the crystal fi...

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  12. If Delta(0) represents CFSE in an octahedral field, e(g) orbitals lie ...

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  13. If CFSE (Delta(0)) is less than pairing energy (P), the ligand is a ……...

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  14. In a tetrahedral crystal field, the d-orbitals split into …… orbitals ...

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  15. If Delta(t) represents CFSE in a tetrahedral crystal field t(2) .The b...

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  16. The common name of K [PtCl(3) (eta^(2)-C(2)H(4))] is ….. .

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  17. The most common name of bis (cyclopentadienyl) iron is ….. .

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  18. The C-O bond length in C -= O ….. (decreases or increases or remains u...

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  19. The metal present in chlorophyll is ….. And the metal present in vitam...

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  20. The brown ring formed in the test of nitrates with FeSO(4) solution an...

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