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On the basis of valence bond theory, exp...

On the basis of valence bond theory, explain geometry, nature of hybridisation, magnetic property and optical isomerism of `[Co(o x)_(3)]^(3-) and [CoF_(6)]^(3-)`.

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To solve the question regarding the coordination compounds \([Co(ox)_3]^{3-}\) and \([CoF_6]^{3-}\) based on valence bond theory, we will analyze each compound step by step, focusing on geometry, hybridization, magnetic properties, and optical isomerism. ### Step 1: Analyze \([Co(ox)_3]^{3-}\) 1. **Determine the oxidation state of cobalt**: - Oxalate (\(ox\)) has a charge of \(-2\). - The overall charge of the complex is \(-3\). - Let the oxidation state of cobalt be \(x\). ...
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PRADEEP-CORDINATION COMPOUNDS-Conceptual Questions
  1. Write the name (IUPAC norms) and draw the possible optical isomers of ...

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  2. A coordination compound has the formula, CoCl(3).4NH(3). It does not l...

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  3. On the basis of valence bond theory, explain geometry, nature of hybri...

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  4. Arrange the following complexes in the increasing order of conductivit...

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  5. The molar conductivity of the complex CoCl(3).4NH(3).2H(2)O is found t...

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  6. A coordination compound CrCI(3).4H(2)O precipitates AgCI when treated ...

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  7. When a coordination compound CrCl(3).6H(2)O is mixed with AgNO(3), 2 m...

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  8. [Co(CN)(6)]^(3-) and [CoF(6)]^(3-) both are octahedral complexes. Then...

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  9. Account for the fact that [Ni(CO)(4)] has tetrahedral geometry whereas...

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  10. Explain how two complexes of nickel, [Ni(CN)4]^(2-) and Ni(CO)4 have d...

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  11. Some square planar complexes of Ni(II) are diamagnetic while some othe...

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  12. Account for different magnetic behaviour of hexacyanoferrate (III) and...

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  13. Out of tetracarbonyl nickel (0) and tetraamminecopper (II) sulphate, w...

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  14. Describe for any two of the following complex ions , the type of hybri...

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  15. Define crystal field splitting energy. On the basis of crystal field t...

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  16. On the basis of crystal field theory, write the electronic configurati...

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  17. A metal ion M^(n+) HAVING D^(4) valence electronic configuration combi...

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  18. Draw a sketch to show the splitting of d-orbitals in an octahedral cry...

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  19. [Ti(H(2)O)(6)]^(3+) is coloured while [Sc(H(2)O)(6)]^(3+) is colourl...

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  20. A solution of [Ni(H(2)O)(6)]^(2+) is green but a solution of [Ni(CN)(4...

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