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Draw isomers of the complex ion [Co(en)(...

Draw isomers of the complex ion `[Co(en)_(2)Cl_(2)]^(+)`

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(i) Write the geometrical isomer of the complex [Co(en)_(2)Cl_(2)]^(+) . (ii) [NiCl_(4)]^(2-) is paramagnetic while [Ni(CN)_(4)]^(2-) is diamagnetic through both are tetrahedral . Why ?

(a) For the complex [Fe(CN)_(6)]^(3-) , write the hybridisation type, magnetic character and spin nature of the complex .(At. Number : Fe = 26) (b) Draw one of the geometrical isomers of the complex [Pt(en)_(2)Cl_(2)]^(2+) which is optically active .

PRADEEP-CORDINATION COMPOUNDS-Important Questions
  1. Write the IUPAC names of the following coordination compounds: (a)[P...

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  2. Write the formulas for the following coordination compounds: (a) Tet...

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  3. Draw isomers of the complex ion [Co(en)(2)Cl(2)]^(+)

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  4. Why is geometrical isomerism not possible in tetrahedral complexes hav...

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  5. Draw all the isomers (geometrical and optical) of: (i) [CoCl(2)(en)(...

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  6. A complex has empirical formula, PtCl(2).2 NH(3). When mixed with AgNO...

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  7. The molar conductivity of the complex CoCl(3).4NH(3).2H(2)O is found t...

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  8. Account for different magnetic behaviour of hexacyanoferrate (III) and...

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  9. Explain on the basis of valence bond theory that [Ni(CN)(4)]^(2-) ion ...

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  10. [NiCl(4)]^(2-) is paramagnetic while [Ni(CO)(4)] is diamagnetic though...

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  11. Explain [Co(NH3)6]^(3+) is an inner orbital complex whereas [Ni(NH3)6]...

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  12. The spin only magnetic moment of [MnBr(4)]^(2-) is 5.9 B.M. Geometry o...

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  13. A solution of [Ni(H(2)O)(6)]^(2+) is green but a solution of [Ni(CN)(4...

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  14. Amongst the following ions, which one has the highest magnetic moment ...

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  15. For the complex [Fe(en)(2)Cl(2)]Cl (en = ethylene diamine ) , identify...

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  16. (a) What happens to the colour of coordination compound [Ti(H(2)O)(6)]...

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  17. Explain the following cases giving appropriate reasons : (i) CuSO(...

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  18. Aqueous copper sulphate solution (blue in colour) gives (i) a green pr...

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  19. (a) Draw a figure to show splitting of degenerate d- orbitals in an oc...

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  20. Why do compounds having similar geometry have different magnetic momen...

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