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Give reasons: (a) n-Butyl bromide has ...

Give reasons:
(a) n-Butyl bromide has higher boiling point than t-butyl bromide.
(b) Racemic mixture is optically inactive.
(c) The presence of nitro group (`-NO_(2)`) at op positions increases the reactivity of haloarenes towards nucleophilic substitution reactions.

Text Solution

Verified by Experts

The presence of `-NO_(2)` groups at o/p-position withdraws electrons from the benzene ring and thus facilitates the attack off the nucleophile on the haloarenes. Further, the carbanion thus formed is stabilized by resonance.
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Assertion: n- Buty chloride has higher boiling point than n-butyl bromide Reason C-CI bond is more polar than C-Br bond .

Assertion: n-butyl chloride has lower b.p than n-butyl bromide Reason The b.p inceases with increase in molar mass .

Assertion: Presence of a nitro group at ortho or para position increases the reactivity of haloarenes towards nucleophilic substitution. Reason: Nitro group, being an electron withdrawing group decreases the electron density over the benzene ring.

Assertion (A) Presence of a nitro group at ortho or para position increases the reactivity of haloarenas towards nucleophilic substitution. Reason (R ) Nitro group, being an electron withdrawing group decreases the electron density over the benzene ring.

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