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CH(3)-CH(2)-CH=CH(2)+HBroverset("ROOR (p...

`CH_(3)-CH_(2)-CH=CH_(2)+HBroverset("ROOR (peroxide)")tounderset("Major")((X))+underset("Minor")((Y))XandY` respectively are

A

`BrCH_(2)CH_(2)-CH=CH_(2) and C_(2)H_(5)-CHBr-CH_(3)`

B

`C_(2)H_(5)-CH_(2)CH_(2)-Br and Br-CH_(2)CH_(2)CH=CH_(2)`

C

`C_(2)H_(5)-CH_(2)CH_(2)-Br and C_(2)H_(5)-CHBr-CH_(3)`

D

`C_(2)H_(5)-CHBr-CH_(3) and C_(2)H_(5)-CH_(2)CH_(2)Br`

Text Solution

Verified by Experts

The correct Answer is:
C
In presence of peroxides, addition of HBr follows anti-Markovnikov's rule.
`CH_(3)CH_(2)CH=CH_(2)+HBr underset(("Anti-Mark. Addn."))overset(ROOR)to underset((X))(CH_(3)CH_(2)CH_(2)CH_(2)Br)+underset((Y))(CH_(3)CH_(2)-CHBr-CH_(3))`
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