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The intermediate during the addition of ...

The intermediate during the addition of `HCl` to propene in the presence of peroxide is :

A

`CH_(3)overset(**)(C)HCH_(2)Cl`

B

`CH_(3)overset(+)(C)HCH_(3)`

C

`CH_(3)CH_(2)overset(**)(C)H_(2)`

D

`CH_(3)CH_(2)overset(+)(C)H_(2)`

Text Solution

Verified by Experts

The correct Answer is:
B
Anti-Markovnikov's addition is observed only with HBr. Therefore, with HCl, even in the presence of peroxides, reaction occurs through a more stable carbocation intermediate, i.e., option (b) is correct.
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