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Consider the following bromides: Th...

Consider the following bromides:

The correct order of `S_(N)1` reactivity is

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The correct Answer is:
C

The reactivity in `S_(N)1` reactions depends upon the stability of the intermediate carbocations. Since the stability of the carbocations derived from (A), (B) and (C) follows the order:

therefore, `S_(N)1` reactivity of these three bromides follows the order: BgtCgtA, i.e., option (c) is correct.
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PRADEEP-HALOALKANES AND HALOARENES-Competition Focus (JEE (MAIN AND ADVANCED)/MEDICAL ENTRANCE SPECIAL (MULTIPLE CHOICE QUESTIONS - I))
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  2. Which one is most reactive towards S(N)1 reactions ?

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  3. Consider the following bromides: The correct order of S(N)1 react...

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  4. The order of rate of hydrolysis of alkyl halides 1^(@),2^(@),3^(@) and...

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  5. The increasing order of hydrolysis of the following compounds is

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  6. The organic chloro compound, which shows complete stereochemical inver...

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  7. The major product of the following reaction is

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  8. In a S(N)2 substitution reaction of the type R-Br+Cl^(-) overset("DM...

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  9. Consider the reaction : CH(3)CH(2)CH(2)Br+NaCNrarrCH(3)CH(2)CH(2)CN+...

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  10. Arrange the following carbanions in order of their decreasing stabilit...

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  11. KI in acetone, undergoes S(N)2 reaction with each of P,Q,R and S. The ...

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  12. In S(N)2 reaction, the correct order of reactivity for following compo...

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  13. In an S(N)1reaction on chiral centres, there is

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  14. Identify the set of reagents/ reaction condition ‘X’ and ‘Y’ in the fo...

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  15. The ease of dehydrohalogenation of alkyl halide with alcoholic KOH is-

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  16. Which of the following organohalogen compound when heated with alcohol...

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  17. For the following reaction : (A) CH(3)CH(2)CH(2)Br+KOH to CH(3)CH=CH...

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  18. The major product formed in the reaction is: CH(3)-underset(H)unders...

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  19. underset(("major"))(B) underset(CH(3)CH(2)OH)overset(CH(3)CH(2)O^(-)Na...

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  20. 2-chloro-2-methylpentane on reaction with sodium methoxide in methanol...

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