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Explain why during preparation of ammoni...

Explain why during preparation of ammonia derivatives from aldehdyes nad ketones, pH of the reaction is carefully controlled.

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Aldehydes and ketones undergo nucleophilic addition reactions. With weak nucleophiles such as ammonia and its derivatives, (H_2 N-Z) , aldehydes and ketones react in weakly acidic medium to form compounds containing carbonnitrogen double bond with the elimination of water to form . Aldehydes can be easily oxidised to carboxylic acid on treatment with common oxidising agents like KMnO_4 K_2 Cr_2 O_7 , HNO_3 , etc. The carboxylic acid formed contain the same number of carbon atoms as the aldehydes. However ketones under drastic conditions with powerful oxidising agents undergo cleavage of C-C bond giving mixture of carboxylic acids having lesser number of C atoms than the original ketone. Name the product formed when formaldehyde reacts with ammonia.

Aldehydes and ketones undergo nucleophilic addition reactions. With weak nucleophiles such as ammonia and its derivatives, (H_2 N-Z) , aldehydes and ketones react in weakly acidic medium to form compounds containing carbonnitrogen double bond with the elimination of water to form . Aldehydes can be easily oxidised to carboxylic acid on treatment with common oxidising agents like KMnO_4 K_2 Cr_2 O_7 , HNO_3 , etc. The carboxylic acid formed contain the same number of carbon atoms as the aldehydes. However ketones under drastic conditions with powerful oxidising agents undergo cleavage of C-C bond giving mixture of carboxylic acids having lesser number of C atoms than the original ketone. Write the reaction of acetone with semicarbazide.

PRADEEP-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS -ADDITIONAL QUESTIONS (SHORT ANSWER QUESTIONS)
  1. Convert ketones into tertiary alcohols.

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  2. Write the names and structures of the products formed in the following...

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  3. Explain why during preparation of ammonia derivatives from aldehdyes n...

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  4. Write the structure of the product formed when semicarbazide reacts wi...

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  5. Write the products of oxidation of (i) 2-pentanone and (ii) 3-pentanon...

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  6. Howare aldehydes distinguished from ketoens using tollen's and fehling...

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  7. how will you distinguish benzaldehyde from (i) Acetaldehyde, (ii) Ac...

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  8. What is haloform reaction? Discuss its utility in organic analysis.

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  9. Formaldehyde and benzaldehyde give cannizzaro reaction but acetaldehyd...

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  10. Why acetaldehyde gives aldol condensation while formaldehyde does not....

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  11. What compound is formed When ethanal is heated with dilute NaOH soluti...

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  12. Write giving chemical equations, a brief account of the following: (...

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  13. v34

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  14. How will you bring about the following conversions in not more...

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  15. Give a chemical test to distinguish between: (i) Acetophenone and be...

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  16. Give two reactions in which aliphatic aldehydes differ from aromatic a...

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  17. Give the IUPAC names of the following: (i) CH(3)-underset(CO(2)H)und...

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  18. Assertion : Carboxylic acids contain a carbonyl group but donot give t...

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  19. Carboxylic acids donot give the characteristic reactions of carbonyl g...

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  20. Acetonitrile is prepared by reacting an alcoholic solution of methyl i...

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