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Predict the product (B) in the following...

Predict the product (B) in the following sequence of reactions:
Ethylbenzene `underset(Delta)overset(KMnO_(4)-KOH)to A overset(H_(3)O^(+))toB`

A

benzaldehyde

B

benzophenone

C

benzene

D

acetophenone

Text Solution

AI Generated Solution

The correct Answer is:
To predict the product (B) in the given sequence of reactions, we start with ethylbenzene and follow the steps outlined in the problem. ### Step-by-Step Solution: 1. **Identify the starting compound**: The starting compound is ethylbenzene, which has the chemical structure \( C_6H_5CH_2CH_3 \). 2. **First reaction with KMnO4 in basic medium**: - Ethylbenzene undergoes oxidation when treated with potassium permanganate (KMnO4) in a basic medium (KOH). - KMnO4 is a strong oxidizing agent and will oxidize the side chain (the ethyl group) of ethylbenzene. - The oxidation of the ethyl group leads to the formation of benzoate ion (the deprotonated form of benzoic acid). The reaction can be summarized as: \[ C_6H_5CH_2CH_3 \xrightarrow{KMnO_4, KOH} C_6H_5COO^{-} \] - Here, the ethyl group is converted to a carboxylate ion (benzoate ion). 3. **Second reaction with H3O+**: - The next step involves the addition of \( H_3O^+ \) (hydronium ion), which will protonate the benzoate ion formed in the previous step. - This protonation converts the benzoate ion into benzoic acid: \[ C_6H_5COO^{-} + H_3O^{+} \rightarrow C_6H_5COOH \] - Therefore, the final product (B) is benzoic acid. ### Final Answer: The product (B) is **benzoic acid** (\( C_6H_5COOH \)).

To predict the product (B) in the given sequence of reactions, we start with ethylbenzene and follow the steps outlined in the problem. ### Step-by-Step Solution: 1. **Identify the starting compound**: The starting compound is ethylbenzene, which has the chemical structure \( C_6H_5CH_2CH_3 \). 2. **First reaction with KMnO4 in basic medium**: - Ethylbenzene undergoes oxidation when treated with potassium permanganate (KMnO4) in a basic medium (KOH). ...
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