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How can you convert an amide into an ami...

How can you convert an amide into an amine having one carbon atom less than the starting compound?

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By Hofmann-bromamide reaction, i.e., by heating a `1^(@)` amide with `Br_(2)` and KOH.
`underset(1^(@)" Amide")(R-CONH_(2))+Br_(2)+4KOH overset(Delta)to underset(1^(@)" Amine (having one carbon atom less than the starting amide)")(R-NH_(2))+K_(2)CO_(3)+2KB r+2H_(2)O`
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How will you convert an amide into an amine with the same number of carbon atoms?

(a) How will you convert an alkyl halide into a primary amine having one more carbon atom than the alkyl halide uses. (b) How can a carboxylic acid be converted into an amine having one more carbon atom than the carboxylic acid used?

How wil you convert an alkene into an aldehyde containing one carboon atom more?

The conversion of an amide into an amine with one carbon atom less by the action of alkaline hydrohalite is known as Hofmann bromamide rearrangement: RCONH_(2) overset(Br_(2)//KOH)toR-NH_(2) The most important feature of the reaction is the arrangement of N–bromamide anion to isocyanate : The product of the reaction Product amine will be :

PRADEEP-ORGANIC COMPOUNDS CONTAINING NITROGEN-ADDITIONAL QUESTIONS (VERY SHORT ANSWER QUESTIONS)
  1. What is ammonolysis?

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  2. How will you convert an amide into an amine with the same number of ca...

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  3. How can you convert an amide into an amine having one carbon atom les...

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  4. Give the IUPAC name and structure of the amine obtained when 3-chlorob...

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  5. Identify A and B in the following sequence of reactions: CH(3)CH(2)B...

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  6. Write the main product of the following reactions: (i) CH(3)-underse...

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  7. Give the structures of A, B and C in the following reaction : CH(3)B...

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  8. How is aminoethane (ethylamine) obtained from ethanal (acetaldehdye)?

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  9. (a) How will you convert an alkyl halide into a primary amine having o...

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  10. How will you obtain the following from methyl isocyanide? (i) dimeth...

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  11. Arrange the following increasing order of their boiling point: C(4)H...

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  12. (a) Arrange the following in the increasing order of boiling points: ...

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  13. Account for the following (i)Primary amines (R-NH(2)) have higher b...

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  14. Methylamine is soluble in water but not aniline. Explain.

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  15. Arrange the following compunds in increasing order of solubility in wa...

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  16. What amine salts are used for determining their molecular masses?

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  17. Why is carbon nitrogen bond length in aromatic amines shorter than in ...

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  18. Why is an alkylamine more basic than ammonia ?

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  19. Which is more acidic (or basic), aniline or ammonia?

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  20. Arrange the following in decreasing order of their basic strength: amm...

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