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Give explanation for each of the follow...

Give explanation for each of the following :
(i) Why are amines less acidic than alcohols of comparable molecular masses ?
(ii). Why do primary amines have higher boiling points han tertiary amines ?
iii. Why are aliphatic amines stroner bases than aromatic amines ?

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Give plausible explanation for each of the following : (i) Why are amines less acidic than alcohols of comparable molecular masses ? (ii). Why do primary amines have higher boiling poings han tertiary amines ? iii. Why are aliphatic amines stroner bases than aromatic amines ?

State reasons for the following: primary amines have higher boiling points than tertiary amines.

Why are boiling points of ethrs lower than those of alcohols of comparable molecular masses ?

PRADEEP-ORGANIC COMPOUNDS CONTAINING NITROGEN-ADDITIONAL QUESTIONS (SHORT ANSWER QUESTIONS)
  1. Write the IUPAC name of diethylamine. How will you obtain it from nitr...

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  2. Why is it difficult to prepare pure amines by ammonolysis of alkyl hal...

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  3. Give explanation for each of the following : (i) Why are amines les...

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  4. Methyl or ethylamine is soluble in water but aniline is insoluble. Exp...

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  5. Account for the following: (i) Secondary amines are more basic than ...

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  6. Why are aromatic amines weaker bases than aliphatic amines? Or pK(b) o...

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  7. Explain K(b) order : Et(2)NH gt Et(3)N gt EtNH(2) in aqueous solution.

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  8. Explain the observed K(b) order: Me(2)NH gt MeNH(2)gt MeN

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  9. In the following cases rearrange the compounds as directed: (i) In a...

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  10. Justify the order of basicity of EtNH(2),Et(2)NH and Et(3)N.

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  11. What is the decreasing order of basicity of 1^(@)2^(@) and 3^(@) ethy1...

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  12. Why is ethylamine more basic than aniline? Explain.

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  13. Give reason: Aniline is a weaker base than cyclohexylamine.

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  14. Explain why aromatic amines are less basic than ammonia and aliphatic ...

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  15. Aniline is less/more basic than ethylamine.

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  16. Explain the following (i) A little acid is always added in the prep...

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  17. What is quaternary ammoniu salt? What happens when triethylamine is he...

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  18. Show the mechanism of acylation of ethanamine and write the IUPAC name...

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  19. Tertiary amines do not undergo acylation. Explain.

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  20. What is carbylamine test for 1^(@) amines?

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