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Account for the following: (i) Seconda...

Account for the following:
(i) Secondary amines are more basic than primary amines.
(ii) Primary amines are more basic than ammonia.
(iii) Arylamines are weaker bases than alkylamines or vice-versa.
(iv) Alkylamines are stronger bases than arylamines.

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PRADEEP-ORGANIC COMPOUNDS CONTAINING NITROGEN-ADDITIONAL QUESTIONS (SHORT ANSWER QUESTIONS)
  1. Give explanation for each of the following : (i) Why are amines les...

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  2. Methyl or ethylamine is soluble in water but aniline is insoluble. Exp...

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  3. Account for the following: (i) Secondary amines are more basic than ...

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  4. Why are aromatic amines weaker bases than aliphatic amines? Or pK(b) o...

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  5. Explain K(b) order : Et(2)NH gt Et(3)N gt EtNH(2) in aqueous solution.

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  6. Explain the observed K(b) order: Me(2)NH gt MeNH(2)gt MeN

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  7. In the following cases rearrange the compounds as directed: (i) In a...

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  8. Justify the order of basicity of EtNH(2),Et(2)NH and Et(3)N.

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  9. What is the decreasing order of basicity of 1^(@)2^(@) and 3^(@) ethy1...

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  10. Why is ethylamine more basic than aniline? Explain.

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  11. Give reason: Aniline is a weaker base than cyclohexylamine.

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  12. Explain why aromatic amines are less basic than ammonia and aliphatic ...

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  13. Aniline is less/more basic than ethylamine.

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  14. Explain the following (i) A little acid is always added in the prep...

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  15. What is quaternary ammoniu salt? What happens when triethylamine is he...

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  16. Show the mechanism of acylation of ethanamine and write the IUPAC name...

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  17. Tertiary amines do not undergo acylation. Explain.

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  18. What is carbylamine test for 1^(@) amines?

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  19. Chloroform when treated with aniline and alcoholic KOH forms -

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  20. Give equations for the reactions that occurs when: (i) Methylamine r...

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