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Explain K(b) order : Et(2)NH gt Et(3)N g...

Explain `K_(b)` order : `Et_(2)NH gt Et_(3)N gt EtNH_(2)` in aqueous solution.

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Electrolysis is an important technique for extraction of metals, and each ion of the solution needs a minimum voltage to get discharged and this value is expressed in terms of discharge potential. For some metal ions the discharge potentials follow the order given below : Li^(+) gt K^(+) gt Ca^(2+) gt Na^(+) gt Mg^(2+) gt Al^(3+) gt Zn^(2+) gt Fe^(2+) gt Ni^(2+) gt H_(3)O^(+) gt Cu^(2+) gt Hg_(2)^(2+) gt Ag^(+) gt Au^(3+) For some anions the discharge potentials are in the order : SO_(4)^(2-) gt NO_(3)^(-) gt OH^(-) gt Br^(-) gt I^(-) When aqueous solution of cupric bromide is electrolyzed the product obtained at cathode will be :

Arrange the following inincreasing order of their basic stregth in aqueous solution: CH_3.NH_2,(CH_3)_3N,(CH_3)_2NH

Which of the following orders is correct? (1) SbH_(3)gt NH_(3) gt AsH_(3) gt PH_(3)-" Boiling Point" (2) NH_(3) gt PH_(3) gt AsH_(3) gt SbH_(3)-" Thermal Stability" (3) NH_(3) gt PH_(3) gt AsH_(3) gt SbH_(3) - "Basic Character" (4) NH_(3) gt PH_(3) gt AsH_(3) gt SbH_(3)- "Bond Angle"

Arrange the following in the increasing order of their basic strength in aqueous solutions: CH_(3)NH_(2), (CH_(3))_(3)N, (CH_(3))_(2)NH

PRADEEP-ORGANIC COMPOUNDS CONTAINING NITROGEN-ADDITIONAL QUESTIONS (SHORT ANSWER QUESTIONS)
  1. Account for the following: (i) Secondary amines are more basic than ...

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  2. Why are aromatic amines weaker bases than aliphatic amines? Or pK(b) o...

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  3. Explain K(b) order : Et(2)NH gt Et(3)N gt EtNH(2) in aqueous solution.

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  4. Explain the observed K(b) order: Me(2)NH gt MeNH(2)gt MeN

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  5. In the following cases rearrange the compounds as directed: (i) In a...

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  6. Justify the order of basicity of EtNH(2),Et(2)NH and Et(3)N.

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  7. What is the decreasing order of basicity of 1^(@)2^(@) and 3^(@) ethy1...

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  8. Why is ethylamine more basic than aniline? Explain.

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  9. Give reason: Aniline is a weaker base than cyclohexylamine.

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  10. Explain why aromatic amines are less basic than ammonia and aliphatic ...

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  11. Aniline is less/more basic than ethylamine.

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  12. Explain the following (i) A little acid is always added in the prep...

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  13. What is quaternary ammoniu salt? What happens when triethylamine is he...

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  14. Show the mechanism of acylation of ethanamine and write the IUPAC name...

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  15. Tertiary amines do not undergo acylation. Explain.

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  16. What is carbylamine test for 1^(@) amines?

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  17. Chloroform when treated with aniline and alcoholic KOH forms -

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  18. Give equations for the reactions that occurs when: (i) Methylamine r...

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  19. Electrophilic substitution in case of aromatic amines takes place more...

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  20. Aniline undergoes electrophilic substitution reactions at ortho-and pa...

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