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The correct order of basicities of the f...

The correct order of basicities of the following compounds is

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The correct Answer is:
B


The conjugate acid (i) obtained by addition of a proton to 1 is stabilized by two equivalent resonance structures and hence compound (1) is the most basic. Further, `2^(@)` amines are more basic than `1^(@)` amines while amides are least basic due to delocalization of lone pair of electrons of N over the C=O group. thus, the order: 1gt3gt2gt4, i.e., option (b) is correct.
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PRADEEP-ORGANIC COMPOUNDS CONTAINING NITROGEN-COMPETITION FOCUS JEE (MAIN AND ADVANCED)/MEDICAL ENTRANCE SPECIAL (MULTIPLE CHOICE QUESTIONS-I)
  1. In pyrrole the electron density is maximum on

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  2. The correct order of basicity of the following

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  3. The correct order of basicities of the following compounds is

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  4. Strongest base is

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  5. Order of the basic strength of the following compounds is

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  6. A compound with molecular mass 180 is acylated with CH(3)COCl to get a...

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  7. In the reaction shown below, the major product formed is/are

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  8. The product formed by the reaction of an aldehyde with a primary amine...

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  9. Reaction of cyclohexanone with dimethylamine in the presence of cataly...

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  10. The major organic product formed from the following reaction

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  11. In the following reactions, the product S is

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  12. On heating an aliphatic primary amine with chloroform and enthanolic p...

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  13. A positive carbylamine test is given by:

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  14. The gas leaked from a storage tank of the Union Carbide plant in Bhopa...

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  15. An organic compound (C3H9N) (A) when treated with nitrous acid , gave ...

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  16. An organic compound 'A' on reduction give compound 'B' which on reacti...

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  17. The optically active compound (X) on treatment with NaNO(2)//HCl ...

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  19. Treatment of cyclobutylmethyamine with nitrous acid does not give .

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  20. The compound which gives an oily nitrosoamine on reaction with nitrous...

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