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A container of volume 1m^(3) is divided ...

A container of volume `1m^(3)` is divided into two equal compartments, one of which contains an ideal gas at 300K. The oterh compartment is vaccum. The whole system is thermally isolated from its surroundings. The partition is removed and the gas expands to occupy the whole volume of the container. Its temperature now would be

A

300K

B

250K

C

200K

D

100K

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To solve the problem step by step, let's analyze the situation: ### Step 1: Understand the System We have a container of volume \(1 \, m^3\) divided into two equal compartments. One compartment contains an ideal gas at a temperature of \(300 \, K\) and the other compartment is a vacuum. ### Step 2: Remove the Partition When the partition is removed, the gas expands to fill the entire volume of the container. Since one side is a vacuum, the gas will undergo free expansion. ### Step 3: Analyze the Thermodynamic Process The system is thermally isolated, which means there is no heat exchange with the surroundings. According to the first law of thermodynamics: \[ \Delta U = Q - W \] Where: - \(\Delta U\) is the change in internal energy, - \(Q\) is the heat added to the system, - \(W\) is the work done by the system. ### Step 4: Determine Heat Transfer and Work Done Since the system is thermally isolated: \[ Q = 0 \] Also, during free expansion into a vacuum, the work done \(W\) is zero: \[ W = 0 \] ### Step 5: Calculate Change in Internal Energy Substituting these values into the first law: \[ \Delta U = 0 - 0 = 0 \] This means the change in internal energy is zero. ### Step 6: Relate Change in Internal Energy to Temperature For an ideal gas, the change in internal energy is given by: \[ \Delta U = n C_v \Delta T \] Where: - \(n\) is the number of moles, - \(C_v\) is the specific heat at constant volume, - \(\Delta T\) is the change in temperature. Since \(\Delta U = 0\), we have: \[ n C_v \Delta T = 0 \] This implies that either \(n = 0\), \(C_v = 0\), or \(\Delta T = 0\). Since the number of moles and specific heat cannot be zero for an ideal gas, we conclude: \[ \Delta T = 0 \] ### Step 7: Final Temperature Calculation Since \(\Delta T = T_{final} - T_{initial} = 0\), we have: \[ T_{final} = T_{initial} \] Given that the initial temperature \(T_{initial} = 300 \, K\), we find: \[ T_{final} = 300 \, K \] ### Conclusion The final temperature of the gas after it expands into the vacuum is \(300 \, K\). ---

To solve the problem step by step, let's analyze the situation: ### Step 1: Understand the System We have a container of volume \(1 \, m^3\) divided into two equal compartments. One compartment contains an ideal gas at a temperature of \(300 \, K\) and the other compartment is a vacuum. ### Step 2: Remove the Partition When the partition is removed, the gas expands to fill the entire volume of the container. Since one side is a vacuum, the gas will undergo free expansion. ...
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