Home
Class 12
CHEMISTRY
For any sparingly soluble salt [M(NH(3))...

For any sparingly soluble salt `[M(NH_(3))_(4)Br_(2)] H_(2)PO_(2)`
Given: `lambda_(M(NH_(3))_(4)Br_(2)^(+))^(@) = 400 Sm^(2) - mol^(-1)`.
`lambda_(H_(2)PO_(2)^(-))^(@) = 100 S-m^(2) -mol^(1)`
Specific resistance of saturated `[M(NH_(3))_(4)Br_(2)] H_(2)PO_(2)` solution is `200 Omega-cm`
If solubility product constant of the above salt is `10^(-x)`. What will be the value of `x`.

Text Solution

Verified by Experts

The correct Answer is:
16

`^^_(m)^(oo) = K xx(1000)/(m) xx 10^(-6)`
`500 = (1)/(200) xx (1000)/(5) xx 10^(-6)`
`S = 10^(-8) mol//L`
`K_(sp) = S^(2) = 10^(-16)`
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    ALLEN|Exercise Part (II) EXERCISE-01|44 Videos
  • ELECTROCHEMISTRY

    ALLEN|Exercise EXERCISE-02|36 Videos
  • ELECTROCHEMISTRY

    ALLEN|Exercise COMPREHENSION TYPE|18 Videos
  • CHEMISTRY AT A GLANCE

    ALLEN|Exercise ORGANIC CHEMISTRY|483 Videos
  • HYDROCARBON

    ALLEN|Exercise MCQ|15 Videos

Similar Questions

Explore conceptually related problems

The pair [Co(NH_(3))_(4)Cl_(2)]Br_(2) and [Co(NH_(3))_(4)Br_(2)]Cl_(2) will show

|Pt(NH_(3))_(4)Cl_(2)|Br_(2) and |Pt(NH_(3))_(4)Br_(2)|Cl_(2) ion are related

For H_(3)PO_(4) , H_(3)PO_(4) hArr H_(2)PO_(4)^(-) + H^(+) (K_(1)) H_(2)PO_(4)^(-) hArr HPO_(4)^(2-) + H^(+) (K_(2)) HPO_(4)^(2-) hArr PO_(4)^(3-) + H^(+) (K_(3)) then

What is the coordination number of Co in [Co(NH_(3))_(4)(H_(2)O)Br](NO_(3))_(2) ?

The solubility of an insoluble phosphate, M_(3)(PO_(4))_(2) of molecular weight w in water is x grams per litre, its solubility product is proportional to

ALLEN-ELECTROCHEMISTRY-INTEGER TYPE
  1. How much charge is present on 1 mole of Cu^(+2) ion in faraday. (1 Far...

    Text Solution

    |

  2. Total charge in faraday present in 54 gm of AI^(3+) ion.

    Text Solution

    |

  3. For an element 'X' the process of oxidation is: X(@)O(4)^(-2) rarr N...

    Text Solution

    |

  4. Consider a Galvenic cell, Zn(s) |Zn^(2+) (0.1M) ||Cu^(2+) (0.1M)|Cu(...

    Text Solution

    |

  5. How much charge (in F) must flow through solution during electrolysis ...

    Text Solution

    |

  6. Emf of a cell corresponding to the reaction:- Zn(s) +2H^(+) (aq) rar...

    Text Solution

    |

  7. A disposable galvanic cell Zn|Zn^(2+)||Sn^(2+)|SN is produced using 1....

    Text Solution

    |

  8. The specific conductance (k)of a 0.1M NaOH solution is 0.0221 S cm^(-1...

    Text Solution

    |

  9. For any sparingly soluble salt [M(NH(3))(4)Br(2)] H(2)PO(2) Given: l...

    Text Solution

    |

  10. An alloy of Pb-Ag weighing 54 mg was dissolved in desired amount of HN...

    Text Solution

    |

  11. A solution contains A^(+) and B^(+) in such a concentration that both ...

    Text Solution

    |

  12. An equeous solution of Na(2)SO(4) was electrolysed for 10 min. 82 ml o...

    Text Solution

    |

  13. At 298K the standard free energy of formation of H(2)O(l) is -256.5 kJ...

    Text Solution

    |

  14. Suppose the equilibrium constant for the reaction, 3M^(3+) rarr 2M^(...

    Text Solution

    |

  15. When a metal chloride MCI is dissolced in a large excess of ammonia, p...

    Text Solution

    |

  16. Molar conductance of 1M solution of weak acid HA is 20 ohm^(-1) cm^(2)...

    Text Solution

    |

  17. While the discharging of a lead storage battery following reaction tak...

    Text Solution

    |

  18. Conductivity of an aqueous solution of 0.1M HX (a weak mono-protic aci...

    Text Solution

    |