Home
Class 12
CHEMISTRY
Calculate the solubiltit and solubility ...

Calculate the solubiltit and solubility product of `Co_(2) [Fe(CN)_(6)]` is water at `25^(@)C` from the following data: conductivity of a saturated solution of `Co_(2)[Fe(CN)_(6)]` is `2.06 xx 10^(-6) Omega^(-1) cm^(-1)` and that of water used `4.1 xx 10^(-7) Omega^(-1) cm^(-1)`. The ionic molar conductivites of `Co^(2+)` and `Fe(CN)_(6)^(4-)` are `86.0 Omega^(-1)cm^(-1) mol^(-1)` and `44.0 Omega^(-1) cm^(-1) mol^(-1)`.

Text Solution

Verified by Experts

The correct Answer is:
`K_(sp) = 7.682 xx 10^(-7)`

`lambda_(M) = (k xx 1000)/(M)`
`(86 xx 2+444) = ((2.06 xx 10^(-6) -4.1xx10^(-7))xx1000)/(s)`
`s = 2.678 xx 10^(-6)`
`K_(sp) = 4s^(3) = 7.687 xx 10^(-17)`
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    ALLEN|Exercise EXERCISE-05 [A]|28 Videos
  • ELECTROCHEMISTRY

    ALLEN|Exercise EXERCISE -05 [B]|38 Videos
  • ELECTROCHEMISTRY

    ALLEN|Exercise EXERCISE-04 [A]|56 Videos
  • CHEMISTRY AT A GLANCE

    ALLEN|Exercise ORGANIC CHEMISTRY|483 Videos
  • HYDROCARBON

    ALLEN|Exercise MCQ|15 Videos

Similar Questions

Explore conceptually related problems

Calculate the solubility product of Co_(2)[Fe(CN)_(6)] in water at 25^(@)C . Given, conductivity of saturated solutions of Co_(2)[Fe(CN)_(6)] is 2.06 xx 10^(-6) Omega^(-1)cm^(-1) and that of water used is 4.1 xx 10^(-7) Omega^(-1)cm^(-1) . The ionic molar conductivities of Co^(2+) and [Fe(CN)_(6)]^(4) are 86.0 Omega cm^(2)mol^(-1) and 444.0 Omega^(-1) cm^(2)mol^(-1) , respectivly.

What is the molarity of Fe(CN)_(6)^(4-) in a saturated solution of Ag_(4)[Fe(CN)_(6)] ? (K_(sp)=1.6xx10^(-41))

The specific conductance of saturated solution of AgCl is found to be 1.86xx10^(-6) ohm^(-1) cm^(-1) and that of water is 6 xx 10^(-8) ohm^(-1) cm^(-1) . The solubility of agCl is ... . Given, Lambda_(AgCl)^(@)=137.2 ohm^(-1) cm^(2) eq^(-1)

The specific conductivity of a saturated AgCI solution if found to be 2.12 xx 10^(-6)S cm^(-1) and that for water is 6 xx 10^(-8)S cm^(-1) . The solubility of AgCI is: (lambda_(eq)^(prop) = 103 S "equiv"^(-1) cm^(2))

The Conductivity of 0.02M Ag NO_(3) at 25^(@)C is 2.428 xx 10^(-3) Omega^(-1) cm^(-1) . What is its molar conductivity?

ALLEN-ELECTROCHEMISTRY-EXERCISE-04 [B]
  1. 10g fairly concentrated solution of CuSO(4) is electrolyzed using 0.01...

    Text Solution

    |

  2. One of the methods of preparation of per disulphuric acid, H(2)S(2)O(8...

    Text Solution

    |

  3. Assume that impure copper contains only iron, silver and a gold as imp...

    Text Solution

    |

  4. For galvanic cell: Ag|AgCI(s), KCI(0.2M|| KBr (0.001M), AgBr(s)|Ag C...

    Text Solution

    |

  5. An aqueous solution of NaCI on electrolysis gives H(2(g)), CI(2(g)) an...

    Text Solution

    |

  6. An acidic solution of Cu^(2+) salt containing 0.4g of Cu^(2+) is elect...

    Text Solution

    |

  7. In the refining of silver by electrolytic method what will be the weig...

    Text Solution

    |

  8. Hydrogen peroxide can be prepared by successive reaction: 2NH(4)HSO(...

    Text Solution

    |

  9. Dal lake has water 8.2 xx 10^(12)litre approximately. A power reactor ...

    Text Solution

    |

  10. Determine the degree of hydrolysis and hydrolysis constant of aniline ...

    Text Solution

    |

  11. The emf of the cell, Pt|H(2)(1atm)|H^(+) (0.1M, 30mL)||Ag^(+) (0.8M)Ag...

    Text Solution

    |

  12. A dilute aqueous solution of KCI was placed between two electrodes 10 ...

    Text Solution

    |

  13. 100mL CuSO(4)(aq) was electrolyzed using inert electrodes by passing 0...

    Text Solution

    |

  14. Calculate the equilibrium concentration of all ions in an ideal soluti...

    Text Solution

    |

  15. Determine at 298 for cell: Pt|Q, QH(2), H^(+) ||1M KCI |Hg(2)CI(2)|H...

    Text Solution

    |

  16. At 25^(@)C, DeltaH(f)(H(2)O,l) =- 56700 J//mol and energy of ionizatio...

    Text Solution

    |

  17. Calculate the cell potential of a cell having reaction Ag(2)S +2e^(-) ...

    Text Solution

    |

  18. Calculate the solubiltit and solubility product of Co(2) [Fe(CN)(6)] i...

    Text Solution

    |

  19. A sample of water from a large swimming pool has a resistance of 9200 ...

    Text Solution

    |

  20. Carefully observe the given figure and using data provided find the EM...

    Text Solution

    |