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In the standardization of Na(2)S(2)O(3) ...

In the standardization of `Na_(2)S_(2)O_(3)` using `K_(2)Cr_(2)O_(7)` by iodometry, th equivalent weight of `K_(2)Cr_(2)O` is

A

`("molecular weight")//2`

B

`("molecular weight")//6 `

C

`("molecular weight")//3`

D

Same as molecular weight

Text Solution

Verified by Experts

The correct Answer is:
B

`({:(Cr_(2)O_(7)^(2-)+14H^(+),+6e^(-) rarr2C^r^(3+),+7 H_(2)O),(,2l^(-)rarrI_(2)+2e^(-)x3,):})/({:(Cr_(2)O_(7)^(2-),+14H^(+)+6I^(-)rarr2C^(3+)+3I_(2),+7H_(2)O),(,so eq.wt.=("Molecular weight")/(6),):})`
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