Home
Class 12
CHEMISTRY
The E^(@) value in respect of the electr...

The `E^(@)` value in respect of the electrodes `(Z=24)`, manganese `(Z=25)` and iron `(Z=26)` are : `Cr^(3+)//Cr^(2+)=-0.4V,Mn^(3+)//Mn^(2+)=+1.5V`, " " `Fe^(3+)//Fe^(2)=+0.8V`.
On the basic of the above information compare the feasibilities of further oxidation of their `+2` oxidation states.

Text Solution

Verified by Experts

The correct Answer is:
`-ve` value of `E^(@)` for `Cr^(3+)//Cr^(2+)` shows that `Cr^(2+)` is least stable. Greater `+ve` valye for `Mn^(3+)//Mn^(2+)` than that for `Fe^(3+)//Fe^(2+)` show that `Mn^(2+)` is more stable than `Fe^(2+)`. Hence , stability of `+2` oxidation state is in the order: `Cr^(2+)ltFe^(2+)ltMn^(2+)` or the oxidation of their `+2` state to `+3` state is in the order :`Cr^(2+)gtFe^(2+)gtMn^(2+)`.
Promotional Banner

Topper's Solved these Questions

  • D BLOCK ELEMENTS

    RESONANCE|Exercise EXERCISE-3 PART-II|26 Videos
  • D & F BLOCK ELEMENTS

    RESONANCE|Exercise INORGANIC CHEMISTRY(d & f- Block Elments)|40 Videos
  • DPP

    RESONANCE|Exercise QUESTIONS|223 Videos

Similar Questions

Explore conceptually related problems

For Mn^(3+)//Mn^(2+) system, the E^(0) values for some metals are as follows: Cr^(3+)//Cr^(2+)(-0.4V) , Mn^(3+)//Mn^(2+) (+1.5V) , Fe^(3+)//Fe^(2+)(+0.8V) . Then the relative stabilities of Fe^(3+), Cr^(3+) and Mn^(3+) is :

For M^(2+)//M and M^(3+)//M^(2+) system, the E^(@) value of some metals are given : Cr^(2+)//Cr=0.9V,Cr^(3+)//Cr^(2+)=-0.4V Mn^(2+)//Mn=1.2V,Mn^(3+)//Mn^(2+)= +1.5 V Fe^(2+)//Fe=0.4 V, Fe^(3+)//Fe^(2+)= +0.8 V Use this data to comment upon : (a) The stability of Fe^(3+) in acid solution as compared to that of Cr^(3+) or Mn^(3+) (b) The ease with which iron can be oxidised as compared to the similar process for either chromium or manganese metal.

Magnetic moment of Cr(Z=24), Mn^+(Z=25) and Fe^(2+)(Z=26) are x,y,z. They are in order

For M^(2+)//M and M^(3+)//M^(2+) systems the E^(ϴ) values for some metals are as follows: {:(Cr^(2+)//Cr,-0.9V,Cr^(3)//Cr^(2+),-0.4 " V"),(Mn^(2+)//Mn,-1.2V,Mn^(3+)//Mn^(2+),+1.5 " V"),(Fe^(2+)//Fe,-0.4V,Fe^(3+)//Fe^(2+),+0.8 " V"):} Use this data to comment upon: (i) the stability of Fe^(3+) in acid solution as compared to that of Cr^(3+) or Mn^(3+) and (ii) the ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.

Magnetic moment of Cr^(+2)(Z=24),Mn^(+2)(Z=25) and Fe^(2+) (Z=26) are x,y,z. they are in order

RESONANCE-D BLOCK ELEMENTS-EXERCISE-3 PART-III
  1. Why do transition elements show variable oxidation state?

    Text Solution

    |

  2. Give reasons for each of the following: (i) Size of trivalent lantha...

    Text Solution

    |

  3. The E^(@) value in respect of the electrodes (Z=24), manganese (Z=25) ...

    Text Solution

    |

  4. The outer electronic configuration of two members of the lanthanoid se...

    Text Solution

    |

  5. Assign reason for each of the following statement: (i) The largest n...

    Text Solution

    |

  6. Write all posible oxidation state of an element having atomic number 2...

    Text Solution

    |

  7. Why is +2 oxidation state of mmanganese quite stable while the same is...

    Text Solution

    |

  8. How is the variability in oxidation states fo transition metals differ...

    Text Solution

    |

  9. Write the electronic configuration of the element with atomic number 1...

    Text Solution

    |

  10. (a) Describe the general trends in the following properties of the fir...

    Text Solution

    |

  11. How would you account for the fact that the transition metals and thei...

    Text Solution

    |

  12. Assign reasons for the following : (i) The enthalpies of atomisatio...

    Text Solution

    |

  13. How would you account for the fact that actinoids exhibit a larger num...

    Text Solution

    |

  14. (a) Complete the following chemical reaction equation :(i)MnO(4(aq))^(...

    Text Solution

    |

  15. Explain the following observation: (i) Generally there is an increas...

    Text Solution

    |

  16. How would you account for the following? (i) The atomic radii of the...

    Text Solution

    |

  17. Explain the following cases giving appropriate reason: (i) Nickel do...

    Text Solution

    |

  18. (a) Complete the following chemical equation: (i) Cr(2)O(7)^(2-)(aq)...

    Text Solution

    |

  19. How would you account for the following? (i) The atomic radii of the...

    Text Solution

    |

  20. Explain the following observation: (i) Transiton elements generally ...

    Text Solution

    |