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How would you account for the fact that actinoids exhibit a larger number of oxidation state than the corresponding lanthanoids?

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Actinoids show a larger number of oxidation state because the energy gap between `5f,6d` and `7s` subshells is very small and hence all the electrons present in these subshells can participate in bonding whereas lanthanoids show a limited number of oxidation state because the energy gap between `4f` and `5d` subshells is large and all the electrons in the these subshells cannot participate in bonding.
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Explain the following observations: (i) Many of the transition elements are known to form interstitial compounds. (ii) There is a general increase in density from titanium (Z = 22) to copper (Z = 29). (iii) The members of the actinoid series exhibit a larger number of oxidation states than the corresponding members of the lanthanoid series.

How would you account for the following ? (i) With the same d-orbital configuration (d^(4)) Cr^(2+) is reducting agent while Mn^(3+) is an oxidizing agent. (ii) The actionoids exhibits a larger numbe of oxidation states than the corresponding members in the lanthanoid series. (iii) Most of the transition metal ions exhibit characteristic in colours in aqueous solutions.

How will you account for the following: (a) Actinoids exhibit more number of oxidation states than lanthanoids. (b) Atomic radii of second and third transition series elements are almost identical.

The actinoids exhibit more number of oxidation states in general than the lanthanoids. This is because

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(a) Silver atom has completely filled 'd' orbitals (4d^10) in its ground state. How can you say that it is a transition element ? (b) Actinoids exhibit a large number of oxidation states in comparison to corresponding members of Lanthanoid series. Why?

RESONANCE-D BLOCK ELEMENTS-EXERCISE-3 PART-III
  1. (a) Describe the general trends in the following properties of the fir...

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  2. How would you account for the fact that the transition metals and thei...

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  3. Assign reasons for the following : (i) The enthalpies of atomisatio...

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  4. How would you account for the fact that actinoids exhibit a larger num...

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  5. (a) Complete the following chemical reaction equation :(i)MnO(4(aq))^(...

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  6. Explain the following observation: (i) Generally there is an increas...

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  7. How would you account for the following? (i) The atomic radii of the...

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  8. Explain the following cases giving appropriate reason: (i) Nickel do...

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  9. (a) Complete the following chemical equation: (i) Cr(2)O(7)^(2-)(aq)...

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  10. How would you account for the following? (i) The atomic radii of the...

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  11. Explain the following observation: (i) Transiton elements generally ...

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  12. What is meant by the 'lanthanide contraction'? Mention one important f...

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  13. How would you account for the following: (i) Cr^(2+) is reducing in ...

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  14. Complete the following chemical equation: (i) MnO(4)^(-)(aq)+s(2)O(3...

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  15. Assign reasons for the following : (i) Copper (I) ion is not known i...

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  16. Complete the following chemical equation: (i) MnO(4)^(-)(aq)+s(2)O(3...

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  17. How would you account for the following : (i) Among lanthanoids,Ln(I...

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  18. How would you account for the following ? (i) Many of the transition...

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  19. (a) Which metal in the first transition series (3d series) exhibits+ 1...

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  20. How would you account for the following? (i) Transition metals exhibi...

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