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How would you account for the following ...

How would you account for the following ?
(i) Many of the transition elements are known to form interstitial compounds.
(ii) The metallic radii of the third `(5d)` series of transition metals are virtually the same as those of the corresponding group members of the second `(4d)` series
(iii) Lanthanoids from primarily +3 ions, while the actinoids +1 usually have higher oxidation state in their compounds ,`+4 or even +6being typical.

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The correct Answer is:
(i) It is because transition elements have voids of suitable size in which small atoms like `H,C,B` etc, can fit into forming interstitial compounds.
(ii) Due to lanthanoid contraction, effective nulcear charge remains almost same therefore , mettalic radii are nearly same
(iii) In Actinoids `5f,6d` and 7s orbitals have comparable energies and electrons fromt these orbitals can take part to show higher oxidation states.
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RESONANCE-D BLOCK ELEMENTS-EXERCISE-3 PART-III
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  2. How would you account for the fact that the transition metals and thei...

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  3. Assign reasons for the following : (i) The enthalpies of atomisatio...

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  4. How would you account for the fact that actinoids exhibit a larger num...

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  5. (a) Complete the following chemical reaction equation :(i)MnO(4(aq))^(...

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  6. Explain the following observation: (i) Generally there is an increas...

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  7. How would you account for the following? (i) The atomic radii of the...

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  8. Explain the following cases giving appropriate reason: (i) Nickel do...

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  9. (a) Complete the following chemical equation: (i) Cr(2)O(7)^(2-)(aq)...

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  10. How would you account for the following? (i) The atomic radii of the...

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  11. Explain the following observation: (i) Transiton elements generally ...

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  12. What is meant by the 'lanthanide contraction'? Mention one important f...

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  13. How would you account for the following: (i) Cr^(2+) is reducing in ...

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  14. Complete the following chemical equation: (i) MnO(4)^(-)(aq)+s(2)O(3...

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  15. Assign reasons for the following : (i) Copper (I) ion is not known i...

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  16. Complete the following chemical equation: (i) MnO(4)^(-)(aq)+s(2)O(3...

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  17. How would you account for the following : (i) Among lanthanoids,Ln(I...

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  18. How would you account for the following ? (i) Many of the transition...

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  19. (a) Which metal in the first transition series (3d series) exhibits+ 1...

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  20. How would you account for the following? (i) Transition metals exhibi...

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