`0.01` mol of a gaseous compound `C_(2)H_(2)O_(x)` was treated with `224 mL` of `O_(2)` at `STP`. After combustion the total volume of the gases is `560 mL` at `STP`. On treatment with `KOH` solution the volume decreases to `112 mL`. The volue of `x` is:
A
`4`
B
`2`
C
`3`
D
None of these
Text Solution
Verified by Experts
The correct Answer is:
A
vol.of `CO_(2) +` vol. of remaining oxygen `= 560 ml`. or vol. of remaining oxygen `= 112 mL` `C_(2)H_(2)O_(x)(g) + ((5-x)/(2))O_(2)(g)overset(Delta)rarr2CO_(2)(g) + H_(2)O(l)` `{:(224 mL,224 mL,0,-),(0,112 mL,448 mL,-):}` for used mole of a`O_(2)`: `((5-x)/(2)) xx 0.1 = (0.01)/(2)` or `x = 4`
Topper's Solved these Questions
TEST PAPERS
RESONANCE|Exercise PART - III CHEMISTRY SEC - 1|12 Videos
TEST PAPERS
RESONANCE|Exercise PART - III CHEMISTRY SEC - 2|18 Videos
SURFACE CHEMISTRY
RESONANCE|Exercise Section - 5|1 Videos
TEST SERIES
RESONANCE|Exercise CHEMISTRY|50 Videos
Similar Questions
Explore conceptually related problems
0.9 gm of a volatile solid organic compound (molecular weight =90) containing carbon, hydrogen and oxygen was heated with 224 ml of oxygen at 1 atm and 0^(@) c. After combustion, the total volume of gases was 560 ml at same T and P. On treatment with KOH, the volume decreased to 112ml. Determine the value of x+y+z if molecular formula of organic compound is C_(x)H_(y)O_(z).
16 " mL of " a gaseous compound C_(n)H_(3n)O_(m) was mixed with 60 " mL of " O_2 and sparked. The gas mixture on cooling occupied 44 mL. After treatment with NaOH solution, the volume of gas remaining was 12 mL. Deduce the formula of the compound.
1 ml of gaseous aliphatic compound C_(n) H_(3n) O_(m) is completely burnt in an excess of O_(2) . The contraction in volume is
The volume of O_(2) at S.T.P required for completely burnt out 100 ml. of ethane is
10 " mL of " a gaseous organic compound containing C, H and O only was mixed with 100 " mL of " O_(2) and exploded under condition which allowed the H_(2)O formed to condense. The volume of the gas after explosion was 90 mL. On treatment with KOH solution, a further contraction of 20 mL in volume was observed. The vapour density of the compound is 23. All volume measurements were made under the same condition. Q.The volume of unreacted O_(2) is
Ten millilitre of a gaseous hydrocarbon was burnt completely in 80 ml of O_2 at STP. The volume of the remaining gas is 70 ml. The volume became 50 ml, on treatment with NaOH . The formula of the hydrocarbon is:
10 " mL of " a gaseous organic compound containing C, H and O only was mixed with 100 " mL of " O_(2) and exploded under condition which allowed the H_(2)O formed to condense. The volume of the gas after explosion was 90 mL. On treatment with KOH solution, a further contraction of 20 mL in volume was observed. The vapour density of the compound is 23. All volume measurements were made under the same condition. Q.The volume of CO_(2) is