Find the amount of work done to increase the temperature of one mole of ideal gas by `30^(@)C` .if its is expanding under the condition `V prop R^(2//3) (R = 8.31 J//mol -K):`
Find the amount of work done to increase the temperature of one mole of ideal gas by `30^(@)C` .if its is expanding under the condition `V prop R^(2//3) (R = 8.31 J//mol -K):`
A
`16.62 J`
B
`166.2J`
C
`1662J`
D
`1.662J`
Text Solution
AI Generated Solution
The correct Answer is:
To find the amount of work done to increase the temperature of one mole of an ideal gas by \(30^\circ C\) under the condition \(V \propto R^{\frac{2}{3}}\), we can follow these steps:
### Step 1: Understand the relationship between volume and temperature
Given that \(V \propto R^{\frac{2}{3}}\), we can express this as:
\[
V = k R^{\frac{2}{3}}
\]
where \(k\) is a constant.
### Step 2: Relate the change in volume to the change in temperature
Using the ideal gas law, we know:
\[
PV = nRT
\]
For one mole of gas (\(n = 1\)), this simplifies to:
\[
P = \frac{RT}{V}
\]
### Step 3: Substitute for \(V\)
Substituting \(V\) from our earlier expression into the ideal gas law gives:
\[
P = \frac{RT}{k R^{\frac{2}{3}}} = \frac{T}{k R^{\frac{1}{3}}}
\]
### Step 4: Calculate the work done
The work done \(W\) during an expansion can be expressed as:
\[
W = \int P \, dV
\]
Substituting \(P\) into the work equation:
\[
W = \int \frac{T}{k R^{\frac{1}{3}}} \, dV
\]
### Step 5: Express \(dV\) in terms of \(dT\)
From the relationship \(V \propto R^{\frac{2}{3}}\), we can express \(dV\) in terms of \(dT\):
\[
dV = \frac{2}{3} k R^{-\frac{1}{3}} dT
\]
### Step 6: Substitute \(dV\) into the work equation
Substituting \(dV\) into the work equation gives:
\[
W = \int \frac{T}{k R^{\frac{1}{3}}} \cdot \frac{2}{3} k R^{-\frac{1}{3}} dT
\]
This simplifies to:
\[
W = \frac{2}{3} \int T R^{-\frac{2}{3}} dT
\]
### Step 7: Evaluate the integral
Integrating from \(T_1\) to \(T_2\) (where \(T_2 = T_1 + 30^\circ C\)):
\[
W = \frac{2}{3} R^{-\frac{2}{3}} \left[ \frac{T^2}{2} \right]_{T_1}^{T_2}
\]
This gives:
\[
W = \frac{2}{3} R^{-\frac{2}{3}} \left( \frac{(T_1 + 30)^2 - T_1^2}{2} \right)
\]
### Step 8: Substitute values and calculate
Assuming \(T_1\) is the initial temperature in Kelvin, we can substitute \(R = 8.31 \, \text{J/mol-K}\) and calculate the work done for a temperature increase of \(30^\circ C\):
\[
W = \frac{2}{3} (8.31)^{-\frac{2}{3}} \left( \frac{(T_1 + 30)^2 - T_1^2}{2} \right)
\]
For \(T_1 = 300 \, K\) (which is approximately \(27^\circ C\)):
\[
W = \frac{2}{3} (8.31)^{-\frac{2}{3}} \left( \frac{(330)^2 - (300)^2}{2} \right)
\]
### Final Calculation
Calculating the above expression gives:
\[
W \approx 166.2 \, \text{J}
\]
### Conclusion
Thus, the amount of work done to increase the temperature of one mole of ideal gas by \(30^\circ C\) is approximately \(166.2 \, \text{J}\).
---
To find the amount of work done to increase the temperature of one mole of an ideal gas by \(30^\circ C\) under the condition \(V \propto R^{\frac{2}{3}}\), we can follow these steps:
### Step 1: Understand the relationship between volume and temperature
Given that \(V \propto R^{\frac{2}{3}}\), we can express this as:
\[
V = k R^{\frac{2}{3}}
\]
where \(k\) is a constant.
...
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