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Find the amount of work done to increase...

Find the amount of work done to increase the temperature of one mole of ideal gas by `30^(@)C` .if its is expanding under the condition `V prop R^(2//3) (R = 8.31 J//mol -K):`

A

`16.62 J`

B

`166.2J`

C

`1662J`

D

`1.662J`

Text Solution

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The correct Answer is:
To find the amount of work done to increase the temperature of one mole of an ideal gas by \(30^\circ C\) under the condition \(V \propto R^{\frac{2}{3}}\), we can follow these steps: ### Step 1: Understand the relationship between volume and temperature Given that \(V \propto R^{\frac{2}{3}}\), we can express this as: \[ V = k R^{\frac{2}{3}} \] where \(k\) is a constant. ### Step 2: Relate the change in volume to the change in temperature Using the ideal gas law, we know: \[ PV = nRT \] For one mole of gas (\(n = 1\)), this simplifies to: \[ P = \frac{RT}{V} \] ### Step 3: Substitute for \(V\) Substituting \(V\) from our earlier expression into the ideal gas law gives: \[ P = \frac{RT}{k R^{\frac{2}{3}}} = \frac{T}{k R^{\frac{1}{3}}} \] ### Step 4: Calculate the work done The work done \(W\) during an expansion can be expressed as: \[ W = \int P \, dV \] Substituting \(P\) into the work equation: \[ W = \int \frac{T}{k R^{\frac{1}{3}}} \, dV \] ### Step 5: Express \(dV\) in terms of \(dT\) From the relationship \(V \propto R^{\frac{2}{3}}\), we can express \(dV\) in terms of \(dT\): \[ dV = \frac{2}{3} k R^{-\frac{1}{3}} dT \] ### Step 6: Substitute \(dV\) into the work equation Substituting \(dV\) into the work equation gives: \[ W = \int \frac{T}{k R^{\frac{1}{3}}} \cdot \frac{2}{3} k R^{-\frac{1}{3}} dT \] This simplifies to: \[ W = \frac{2}{3} \int T R^{-\frac{2}{3}} dT \] ### Step 7: Evaluate the integral Integrating from \(T_1\) to \(T_2\) (where \(T_2 = T_1 + 30^\circ C\)): \[ W = \frac{2}{3} R^{-\frac{2}{3}} \left[ \frac{T^2}{2} \right]_{T_1}^{T_2} \] This gives: \[ W = \frac{2}{3} R^{-\frac{2}{3}} \left( \frac{(T_1 + 30)^2 - T_1^2}{2} \right) \] ### Step 8: Substitute values and calculate Assuming \(T_1\) is the initial temperature in Kelvin, we can substitute \(R = 8.31 \, \text{J/mol-K}\) and calculate the work done for a temperature increase of \(30^\circ C\): \[ W = \frac{2}{3} (8.31)^{-\frac{2}{3}} \left( \frac{(T_1 + 30)^2 - T_1^2}{2} \right) \] For \(T_1 = 300 \, K\) (which is approximately \(27^\circ C\)): \[ W = \frac{2}{3} (8.31)^{-\frac{2}{3}} \left( \frac{(330)^2 - (300)^2}{2} \right) \] ### Final Calculation Calculating the above expression gives: \[ W \approx 166.2 \, \text{J} \] ### Conclusion Thus, the amount of work done to increase the temperature of one mole of ideal gas by \(30^\circ C\) is approximately \(166.2 \, \text{J}\). ---

To find the amount of work done to increase the temperature of one mole of an ideal gas by \(30^\circ C\) under the condition \(V \propto R^{\frac{2}{3}}\), we can follow these steps: ### Step 1: Understand the relationship between volume and temperature Given that \(V \propto R^{\frac{2}{3}}\), we can express this as: \[ V = k R^{\frac{2}{3}} \] where \(k\) is a constant. ...
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