Home
Class 12
CHEMISTRY
For the reaction : (CH(3))(3)CBr(aq)+O...

For the reaction :
`(CH_(3))_(3)CBr(aq)+OH^(-)(aq)rarr(CH_(3))_(3)COH(aq)+Br^(-)(aq)`
it is found that halving the concentration of `(CH_(3))_(3)CBr` causes the reaction rate to be halved but halving the concentration of `OH^(-)` has no effect on the rate. What is the rate law?

A

Rate = `k[(CH_(3))_(3)CBr]^(1//2)[OH^(-)]`

B

Rate = `k[(CH_(3))_(3)CBr]^(2)[OH^(-)]`

C

`k[(CH_(3))_(3)CBr]^(1//2)`

D

`k[(CH_(3))_(3)CBr]`

Text Solution

Verified by Experts

The correct Answer is:
D
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    GRB PUBLICATION|Exercise C. Integrated Rate Laws|73 Videos
  • CHEMICAL KINETICS

    GRB PUBLICATION|Exercise D. Methods to Determine the Rate Law|28 Videos
  • CHEMICAL KINETICS

    GRB PUBLICATION|Exercise Subjective Type|63 Videos
  • CHEMICAL BONDING-I

    GRB PUBLICATION|Exercise Subjective Type|120 Videos
  • COORDINATION COMPOUNDS

    GRB PUBLICATION|Exercise SBJECTIVE TYPE|98 Videos

Similar Questions

Explore conceptually related problems

Following reaction: (CH_(3))_(3)C-Br +H_(2)O rarr (CH_(3))_(3)C-OH +HBr is an example of -

the reaction: CH_3CH_2I+KOH(aq.)rarrCH_3CH_2OH+KI is classified as:

(CH_(3))_(3)C CH_(2)-CBr(CH_(3))_(2)overset(Heat)rarr The major product is

The reaction H_(2)O_(2)(aq)+3I^(-)(aq)+2H^(+)(aq)rarrI_(3)^(-)(aq)+2H_(2)O(l) has a rate law : rate = k[H_(2)O_(2)][I^(-)] . What is the order of the reaction with respect to H^(+) , and what is the overall order of the reaction?

For the following reaction: (CH_(3))_(3)"CCl"+H_(2)O rarr (CH_(3))_(3)COH+HCl,((dx)/(dt))=k [(CH_(3))_(3)"CCl"] hence , rate determining step can be:

The following reaction is classified as : CH_(3)CH_(2)I+KOH(aq) rarr CH_(3)CH_(2)OH+KI

GRB PUBLICATION-CHEMICAL KINETICS-B. Rate Law
  1. A reaction was found to be second order with respect to the concentrat...

    Text Solution

    |

  2. In which of the following reactions the graph of concentration vs time...

    Text Solution

    |

  3. For a process A + B rarr product, the rate of reaction is second order...

    Text Solution

    |

  4. Propanone reacts with iodine in acid solution as shown in this equatio...

    Text Solution

    |

  5. One litre of 2 M acetic acid and one litre of 3 M ethyl alcohol are m...

    Text Solution

    |

  6. A substance 'A' undergoes conversion by an elementary step to 'B' and ...

    Text Solution

    |

  7. The rate law for a certain reaction is found to be : Rate = k[A][B]^(2...

    Text Solution

    |

  8. The equation and rate law for the gas phase reaction between NO and H(...

    Text Solution

    |

  9. For the reaction : (CH(3))(3)CBr(aq)+OH^(-)(aq)rarr(CH(3))(3)COH(aq)...

    Text Solution

    |

  10. A hypothetical reaction has a rate law of : Rate = k[A]^(2)[B]. Whic...

    Text Solution

    |

  11. Under certain conditions the reaction of CO with NO(2) to give CO(2) a...

    Text Solution

    |

  12. Factor that can affect the rate of a chemical reaction between a solid...

    Text Solution

    |

  13. Consider the hypothetical reaction : A + 2B rarr C The rate remains co...

    Text Solution

    |

  14. For the reaction: 2A+3BrarrC,[A] is found to decrease at a rate of 2...

    Text Solution

    |

  15. The reaction H(2)O(2)(aq)+3I^(-)(aq)+2H^(+)(aq)rarrI(3)^(-)(aq)+2H(2)O...

    Text Solution

    |

  16. For the reaction 2H(2)(g)+2NO(g)rarrN(2)(g)+2H(2)O(g) Rate = k[H(2...

    Text Solution

    |

  17. A + 2B rarr C, the rate equation for this reaction is given as Rate ...

    Text Solution

    |

  18. For a rate law of the form, Rate = k[A]^(m)[B]^(n), the exponents m an...

    Text Solution

    |

  19. The reaction between NO and I(2) is second-order in NO and first-order...

    Text Solution

    |

  20. This reaction is first order with reapect of N(2)O(5). 2N(2)O(5)(g)r...

    Text Solution

    |