Home
Class 12
CHEMISTRY
For the Ist order reaction : A(g) rarr...

For the Ist order reaction :
A(g) `rarr` B(g) + C(g) + D(s)
taking place at constant pressure and temperature condition. Initially volume of container containing only A was found to be 10 L and after `0.693` hrs it was `17.5` L. The rate canstant for the reaction is :

A

`(1)/(0.693)"ln" (3)/(2)hr^(-1)`

B

2 `hr^(-1)`

C

`(1)/(0.693)"ln"(4)/(3)hr^(-1)`

D

1 `hr^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
B
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    GRB PUBLICATION|Exercise D. Methods to Determine the Rate Law|28 Videos
  • CHEMICAL KINETICS

    GRB PUBLICATION|Exercise E. Methods to Monitor the Progress of Reaction|43 Videos
  • CHEMICAL KINETICS

    GRB PUBLICATION|Exercise B. Rate Law|35 Videos
  • CHEMICAL BONDING-I

    GRB PUBLICATION|Exercise Subjective Type|120 Videos
  • COORDINATION COMPOUNDS

    GRB PUBLICATION|Exercise SBJECTIVE TYPE|98 Videos

Similar Questions

Explore conceptually related problems

For the reaction, A(s) + 3B(g) rarr 4C(g) + d(l) Delta H and Delta U are related as :

For a reaction 2A(g)+2B(g) rarr 2C(g)+D(g) . If heat of reaction at constant pressure is -28 K.cal. The heat of reaction at constant volume at 27^(@)C is

Consdier a first order gas phase reaction, A(g) rarr 2B(g) + C(g) The initial pressure taking only A in a rigid vessel was found to be P atme. After a lapse of 10 minutes, the pressure of the system increases by x units and became P_(10) atm. The rate constant for the reaction is given by :

Consider the reaction 2A(g) rarr 3B(g) + C(g) . Starting with pure A initially, the total pressure doubled in 3 hrs. The order of the reaction might possibly be :

a A_((g)) + bB_((g)) rarr cC_((g)) + d D_((g)) Reaction is taking place at constant Temperature, Pressure & Volume, then correct statement(s) is/are:

For the first order reaction A(g) rarr 2B(g) + C(g) , the initial presuure is P_(A) = 90 m Hg , the pressure after 10 minutes is found to be 180 mm Hg . The rate constant of the reaction is

GRB PUBLICATION-CHEMICAL KINETICS-C. Integrated Rate Laws
  1. which is not true for a second order reaction?

    Text Solution

    |

  2. A(g)rarrB(g)+C(g) -(d[A])/(dt)=k[A] At the start, pressure is 100 ...

    Text Solution

    |

  3. For the Ist order reaction : A(g) rarr B(g) + C(g) + D(s) taking p...

    Text Solution

    |

  4. Which of the following statements is correct for a possible order reac...

    Text Solution

    |

  5. In a reaction involving one single reactant, the fraction of the react...

    Text Solution

    |

  6. For an acid catalysed hydrolysis of an ester which of the following op...

    Text Solution

    |

  7. For the reaction : A rarr Product, the order of reaction is equal to ...

    Text Solution

    |

  8. A reaction : A + B rarr C follows the rate law as shown : R=10^(-2) [A...

    Text Solution

    |

  9. The half life period of a first order chemical reaction is 16.93 minut...

    Text Solution

    |

  10. Which of the following reactions is pseudo first order reaction?

    Text Solution

    |

  11. Which of the following options regarding characteristics of zero order...

    Text Solution

    |

  12. For a first order reaction, the concentration decreases to 30% of its ...

    Text Solution

    |

  13. For a gaseous reaction : 2A(g)rarrB(g)+2C(g), the pressure changes fro...

    Text Solution

    |

  14. The inversion of cane sugar proceeds with half life of 50 minutes pH =...

    Text Solution

    |

  15. The reaction Aoverset(k)rarr Products, is zero order while the reactio...

    Text Solution

    |

  16. For the reaction A + 2B rarr products (started with concentration take...

    Text Solution

    |

  17. For a reaction 2A + B rarr product, rate law is -(d[A])/(dt)=k[A]. At ...

    Text Solution

    |

  18. Concentration of the reactant in first-order is reduced to (1)/(e^(2))...

    Text Solution

    |

  19. In a I order reaction A rarr products, the concentration of the reacta...

    Text Solution

    |

  20. Under the same reaction conditions, initial concentration of 1.386 "mo...

    Text Solution

    |