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Inversion of sucrose (C(12)H(22)O(11)) i...

Inversion of sucrose `(C_(12)H_(22)O_(11))` is first-order reaction and is studied by measuring angle of rotation at different instants of time
`underset(d)underset("Sucrose")(C_(12)H_(22)O_(11))+H_(2)Ooverset(H^(+))rarrunderset(d)underset("Glucose")(C_(6)H_(12)O_(6))+underset(l)underset("Fructose")(C_(6)H_(12)O_(6))`
If `(r_(oo)-r_(0))=a` and `(r_(oo)-r_(t))=(a-x)` (where `r_(0),r_(t)` and `r_(oo)`) are the angle of rotation at the start, at the time t and at the end of the reaction respectively, then there is `50%` inversion when :

A

`r_(0)=2r_(t)-r_(oo)`

B

`r_(0)-r_(t)-r_(oo)`

C

`r_(0)=r_(t)-2r_(oo)`

D

`r_(0)=r_(t)+r_(oo_`

Text Solution

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The correct Answer is:
A
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Inverison of sucrose is studied by measuring the angle of rotation at any time t . underset(("Sucrose"))(C_(12)H_(22)O_(11))underset(("Glucose"))(+H_(2)O) overset(H^(o+))rarrunderset(("Fructose"))(C_(6)H_(12))O_(6)+C_(6)H_(12)O_(6) It is found that (r_(oo) - r_(0)) prop a and (r_(oo) - r_(t)) prop, (a-x) , where r_(0), r_(t) , and r_(oo) are the angle of rotation at the start, at the time t , and at the end of the reaction, respectively. Form the following values calculate the rate constant and the time at which the solution is optically inactive. |{:("Time (min)",0.0,46.0,oo),("Rotation of polarized light (degree)",24.1,10.0,-10.7):}|

underset("Sucrose)(C_(12)H_(22)O_(11))+H_(2)O overset(di l. H_(2)SO_(4))(rarr) underset(Fruct ose)(C_(6)H_(12)O_(6)(aq))+underset(Glucose)(C_(6)H_(12)O_(6)(aq)) In this reaction, dilute H_(2)SO_(4) is called

C_(12) H_(22)O_(11) + underset("excess") (H_(2)O) to underset("glucose")(C_(6)H_(12)O_(6) + underset("fructose")(C_(6)H_(12)O_(6) Rate law is expressed as

The oxidation number of C in sucrose (C_(12)H_(22)O_(11)) is

underset("Sucrose")(C_(12)H_(22)O_(11)+H_(2)O) overset("Enzyme A")tounderset("Glucose")(C_(6)H_(12)O_(6))+underset("Fructose")(C_(6)H_(12)O_(6)) underset("Glucose")(C_(6)H_(12)O_(6)) overset("Enzyme B")to2C_(2)H_(5)OH+2CO_(2) In the above reactions, the enzyme A and enzyme B respectively are :

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