Home
Class 12
CHEMISTRY
It is observed that when ozone undergoes...

It is observed that when ozone undergoes decomposition to form `O_(2)`(g) a two step mechanism is observed.
(a) `O_(3)(g)underset(k_(2))overset(k_(1))(hArr) O_(2)(g)+O(g)`
(b)`O_(3)(g)+O(g) overset(k_(3))rightarrow2O_(2)`
Also it is known that `k_(1) gt gt k_(3) and k_(2) gt gt k_(3)`
If `DeltaH` of first reaction is 20 kj and `E_(a)` of second step is 50 kJ then net activation energy will be:

A

50 kJ

B

20 kJ

C

30 kJ

D

70 kJ

Text Solution

Verified by Experts

The correct Answer is:
D
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    GRB PUBLICATION|Exercise Comprehension type 3|1 Videos
  • CHEMICAL KINETICS

    GRB PUBLICATION|Exercise Comprehension type 4|1 Videos
  • CHEMICAL KINETICS

    GRB PUBLICATION|Exercise Comprehension type 2|1 Videos
  • CHEMICAL BONDING-I

    GRB PUBLICATION|Exercise Subjective Type|120 Videos
  • COORDINATION COMPOUNDS

    GRB PUBLICATION|Exercise SBJECTIVE TYPE|98 Videos

Similar Questions

Explore conceptually related problems

It is observed that when ozone undergoes decomposition to form O_(2) (g) a two step mechanism is observed. (a) O_(3)(g)underset(k_(2))overset(k_(1))(hArr) O_(2)(g)+O(g) (b) O_(3)(g)+O(g) overset(k_(3))rightarrow2O_(2) Also it is known that k_(1) gt gt k_(3) and k_(2) gt gt k_(3) What will be the overall order of the reaction?

It is observed that when ozone undergoes decomposition to form O_(2) (g) a two step mechanism is observed. (a) O_(3)(g)underset(k_(2))overset(k_(1))(hArr) O_(2)(g)+O(g) (b) O_(3)(g)+O(g) overset(k_(3))rightarrow2O_(2) Also it is known that k_(1) gt gt k_(3) and k_(2) gt gt k_(3) If initially mixture of oxygen and ozone is taken such that Ozone is in very large amount, then, identify the correct statement.

Decomposition of ozone follows the given mechanism . From the mechanism select the option which is not correct. Step (i) : O_(3) underset(K_(2))overset(K_(1))hArr O_(2)(g) +O(g)" " [Fast] Step (ii): O_(3)(g) +O(g) overset(K_(3))rarr 2O_(2)(g)" " [Slow]

The mechanism of the reaction 2NO + O_(2) rarr 2NO_(2) is NO + NO underset(k_(-1))overset(k_(1))hArr N_(2)O_(2) ("fast") N_(2)O_(2) + O_(2) overset(k_(2))rarr 2NO_(2) (slow) The rate constant of the reaction is

Consider the following equilibrium: SO_(2)(g)+(1)/(2)O_(2)(g)overset(K_(1))(hArr)SO_(3)(g), 2SO_(3)(g)overset(K_(2))(hArr) What is the relation between K_(1) and K_(2) ?

In the following reaction: 2NO(g)+O_(2)(g) overset(k')rarr2NO_(2)(g) What is the predicted rate law, if the mechanism is NO+O_(2)(g) overset(k_(eq))hArr NO_(3) ("fast") (fast) NO_(3) + NO overset(k_(1))rarr NO_(2) + NO_(2) (slow)

Equilibrium constants K_(1) and K_(2) for the following equilibria NO(g) +1//2O_(2)(g) overset(K_(1))(hArr) NO_(2)(g) and 2NO_(2)(g) overset(K_(2))(hArr)2NO(g)+O_(2)(g) are related as

Ozone deplection takes place as : 2O_(3)(g)rarr3O_(2)(g) Step1: O_(3)(g)overset(k)hArrO_(2)(g)+O(g)" " (fast) Step2 : O_(3)(g)+[O]overset(k)rarr2O_(2)(g)" " (slow) order of the raction will be :

The chemical reaction 2O_(3) overset(k_(1))rarr 3O_(2) proceeds as follows: O_(3) overset(k_(eq))hArr O_(2)+O (fast) O + O_(3) overset(k)rarr 2O_(2) (slow) What should be the rate law expresison ?

Consider the following reversible chemical reactions : A_(2)(g)+B_(2)(g)overset(K_(1))(hArr)2AB(g)....(1) 6AB(g) overset(K_(2))(hArr)3A_(2)(g)+3B_(2)(g).....(2) The relation between K_(1) and K_(2) is :

GRB PUBLICATION-CHEMICAL KINETICS-Comprehension type
  1. It is observed that when ozone undergoes decomposition to form O(2)(g)...

    Text Solution

    |

  2. It is observed that when ozone undergoes decomposition to form O(2)(g)...

    Text Solution

    |

  3. Two liquids A and B mix to form an ideal binary liquid solution On add...

    Text Solution

    |

  4. Radioactive decay follows first order kinetics and the rate constant i...

    Text Solution

    |

  5. Radioactive decay follows first order kinetics and the rate constant i...

    Text Solution

    |

  6. In order to analyse variation of rate constant with temperature Arrhen...

    Text Solution

    |

  7. In order to experimentally determine order, initial rate method can be...

    Text Solution

    |

  8. The general defination of the activation energy E(a) of any rate proce...

    Text Solution

    |

  9. In order to determine order/rate constant of any gaseous reaction pres...

    Text Solution

    |

  10. Fluorine - 18 is a radioactive isotope that decays by positron emissio...

    Text Solution

    |

  11. Fluorine - 18 is a radioactive isotope that decays by positron emissio...

    Text Solution

    |

  12. The solvolysis of cinnamyl chloride can be studied spectrophotometrica...

    Text Solution

    |

  13. In an investigation of the kinetics of the reaction MnO(4)^(-)+Cr^(3...

    Text Solution

    |

  14. In an investigation of the kinetics of the reaction MnO(4)^(-)+Cr^(3...

    Text Solution

    |

  15. A(g) rarr 2B(g)+C(g) Initially at t=0 gas A was present with some a...

    Text Solution

    |

  16. A(g) rarr 2B(g)+C(g) Initially at t=0 gas A was present with some a...

    Text Solution

    |

  17. Set -I (without catalyst) {:(,"Reaction",,"Temperature",,"E(activati...

    Text Solution

    |

  18. Set -I (without catalyst) {:(,"Reaction",,"Temperature",,"E(activati...

    Text Solution

    |

  19. The reaction S(2)O(8)^(2-) + 3I^(-) rarr 2SO(4)^(2-) + I(3)^(-) is of ...

    Text Solution

    |

  20. The reaction S(2)O(8)^(2-) + 3I^(-) rarr 2SO(4)^(2-) + I(3)^(-) is of ...

    Text Solution

    |