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Set -I (without catalyst) {:(,"Reactio...

Set -I (without catalyst)
`{:(,"Reaction",,"Temperature",,"E(activation)",,"k"),(,ArarrB,,T_(1)K,,Ea_(1),,k_(1)),(,A rarr B,,T_(2)K,,Ea_(2),,k_(2)):}`
Set-II (with catalyst) (consider `+ve` catalyst only)
`{:(,"Reaction",,"Temperature",,"E(activation)",,"k"),(,A rarr B,,T_(1)K,,Ea_(3),,k_(3)),(,A rarr B,,T_(2)K,,Ea_(4),,k_(4)):}`
Comparing Set-I and II:

A

`k_(4) gt k_(3) and k_(2)k_(1), if T_(2) gt T_(1)` (endothermic)

B

`k_(4) lt k_(3) and k_(2) gt k_(1) if T_(2) lt T_(1)` (endothermic)

C

`k_(4) gt k_(3) and k_(2) gt k_(1) if T_(2) lt T_(1)` (exothermic)

D

`k_(4) lt k_(3) and k_(2) lt k_(1) , if T_(2) gt T_(1)` (exothermic)

Text Solution

Verified by Experts

The correct Answer is:
A
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