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Study the two photochemical reactions an...

Study the two photochemical reactions and answer the questions given below: For the overall reaction between A and B to yield C and D two mechanisms are proposed:
(I) `A+B rarr AB* rarr C+D, k_(1)=1xx10^(-5)M^(-1)s^(-1)`
(II) `A rarr A* rarr E, k_(1)=1xx10^(-4)M^(-1)s^(-1)`
`E+B rarr C+D, k_(2)=1xx10^(10)M^(-1) s^(-1)` (species with * are short-lived)
Rate according to mechanism I when concentration of each reactant is `0.1` M will be:

A

`1xx10^(-7)M s^(-1)`

B

`1xx10^(-6) M s^(-1)`

C

`1xx10^(-5) M s^(-1)`

D

`1xx10^(-4)M s^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
A
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