Home
Class 12
CHEMISTRY
5 milli-moles of a solid A was dissolved...

5 milli-moles of a solid A was dissolved in 5 moles of `H_(2)O.` On adding to the solvent, A starts polymerising into another insoluble solid following zero order kinetics. On adding 6 milli-moles of another solid solute C (after 20 minute) the polymerisation completely stops. The insoluble solid polymer is removed and the resulting solution was cooled to a temperature less then `.-0.186^(@)C` (freezing point of solution ) to cause solidification of some liquid water . Calculate the value of X if rate constant for polymerisation reaction is represented as `10^(-X)` moles`//`minute.
`[K_(f) (H_(2)O)= 1.86 K - Kg "mole"^(-1)]`

Text Solution

Verified by Experts

The correct Answer is:
4
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    GRB PUBLICATION|Exercise match the column type|13 Videos
  • CHEMICAL BONDING-I

    GRB PUBLICATION|Exercise Subjective Type|120 Videos
  • COORDINATION COMPOUNDS

    GRB PUBLICATION|Exercise SBJECTIVE TYPE|98 Videos

Similar Questions

Explore conceptually related problems

To 250.0 ml of M//50H_(2)SO_(4), 4.0 g of solid NaOH is added and the resulting solution is

6 milli mole of pure gypsum is heated to convert it completely to plaster of paris. What is the number of milli moles of steam evolved in the process?

one of the following repersents the solution of solid in a solid ,this one is :

When 1 mole of a solute is dissolved in 1 kg of H_(2)O , boiling point of solution was found to be 100.5^(@) C. K_(b) for H_(2)O is :

Water is added to the solution M such that the mole fraction of water in the solution becomes 0.9 . The boiling point of this solution is

On freezing an aqueous solution of sodium chloride, the solid that starts separating out is

GRB PUBLICATION-CHEMICAL KINETICS-Subjective Type
  1. For the first order decomposition reaction: 2N(2)O(5) (g) to 4NO(2) ...

    Text Solution

    |

  2. For a gaseous reaction, 2A(g) + B(g) to C(g) , DeltaH =- 30 "Kcal"//...

    Text Solution

    |

  3. 5 milli-moles of a solid A was dissolved in 5 moles of H(2)O. On addin...

    Text Solution

    |

  4. For the first order reaction :A(g) to 2B(g) + C(g) the half life for t...

    Text Solution

    |

  5. For a third order reaction the ratio of t(1//3) "and"t(2//3) is T [t(1...

    Text Solution

    |

  6. For the sequential reaction: A.overset(k(1)=0.2"min"^(-1))(to)Bovers...

    Text Solution

    |

  7. A first order reaction, 3A (g) to 2B(g) + 3C (g) Starting with pu...

    Text Solution

    |

  8. The number of neutrons emitted when .(92)^(235) U undergoes controlled...

    Text Solution

    |

  9. For the reaction A(g) to 2B(g) (d[B])/(dt) = 6xx10^(-4) M sec^(-1) "...

    Text Solution

    |

  10. If activation energy of reaction is given as (2500 + 3T) R then calcul...

    Text Solution

    |

  11. 2A + 3B to 4C is a complex reaction with rate law, r=k[A]^(0) [B]^(1)...

    Text Solution

    |

  12. A tribasic acid ,H(3)A, dissociates into a dibasic acid , H(2)B and a ...

    Text Solution

    |

  13. To carry out metabolim oxygen is taken up by haemoglobin (Hb) to from ...

    Text Solution

    |

  14. An optically active substance A is decomposing into optically active s...

    Text Solution

    |

  15. Gaseous decomposition of A follows Ist order kinetics . Pure A (g) is ...

    Text Solution

    |

  16. For a reaction : A(g) to nB(g) the rate constat is 6.93xx10^(-4) sec^(...

    Text Solution

    |

  17. For the reaction , A (aq) to 2B(aq),50% reaction occurs in 10 min and ...

    Text Solution

    |

  18. For the reaction :A(aq) to 2B(aq) +C(aq), the rate is 2.4xx10^(-3)"m...

    Text Solution

    |

  19. The rate of decomposition for methyl nitrite and ethyl nitrite can be ...

    Text Solution

    |

  20. The rate law of a chemical reaction given below : 2NO(g) + O(2)(g) t...

    Text Solution

    |