Home
Class 11
CHEMISTRY
If bond energy of H(2),F(2) and HF are i...

If bond energy of `H_(2),F_(2)` and `HF` are in the ratio `2:1:3` and `DeltaH_(a)(H_(2))=400kJ//mol`. Then `DeltaH_(f)(HF)` is `:`

A

`0 kJ //mol`

B

`-600kJ //mol`

C

`-1200kJ//mol`

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
4

`DeltaH_(f)(HF)=(1)/(2)DeltaH_(a)(H_(2))+(1)/(2)DeltaH_(a)(F_(2))-DeltaH(HF)-(1)/(2)xx400+(1)/(2)xx200-600=-300kJ//mol.`
Promotional Banner

Topper's Solved these Questions

  • STRUCTURAL IDENTIFICATION & PRACTICAL ORGANIC CHEMISTRY

    RESONANCE|Exercise Section -B|18 Videos

Similar Questions

Explore conceptually related problems

If the bond dissociation energies of XY , X_(2) and Y_(2) are in the ratio of 1:1:0.5 and DeltaH_(f) for the formation of Xy is -200 KJ//mol . The bond dissociation energy of X_(2) will be :-

Given that Bond energy of H_(2) and N_(2) are 400KJmol^(-1) and 240KJmol^(-1) respectively and DeltaH_(f) of NH_(3) is -120KJmol^(-1) calculate the bond energy of N-H bond :-

Calculate the DeltaH_(f)^@ of C_(6)H_(12)O_(6) (s) from the following data: DeltaH_(comb)[C_(6)H_(12)O_(6)(s)]=-2816.kJ//mol DeltaH_(f)^(@) of CO_(2)(g)=-393.5kJ//mol DeltaH_(f)^(@) of H_(2)O(l)=-285.9kJ//mol

The heat of formation (DeltaH_(f)^(@)) of H_(2)O(l) is equal to :

Nitroglycerine (MW =227.1) denotes according to the following equation : 2C_(3)H_(5)(NO_(3))_(3)I to 3N_(2)(g)+1//2O_(2)(g)+6CO_(2)(g)+5H_(2)O(g) The standard molar enthalpies of formation, DeltaH_(f)^(@) for the compounds are given bellow: DeltaH_(f)^(@)[C_(3)H_(5)(NO_(3))_(3)]= -364 kJ//mol DeltaH_(f)^(@)[CO_(2)(g)]= -395.5 kJ//mol DeltaH_(f)^(@)[H_(2)O(g)]= -241.8 kJ//mol DeltaH_(f)^(@)[N_(2)(g)]= 0 kJ//mol DeltaH_(f)^(@)[O_(2)(g)]= 0 kJ//mol The enthalpy change when 10g of nitroglycerine is detonated is

RESONANCE-THERMODYNAMIC & THERMOCHEMISTRY-PHYSICAL CHEMITRY (THERMODYNAMIC & THERMOCHEMISTRY)
  1. A chidl brought a balloon which became very small in size the next day...

    Text Solution

    |

  2. It the following processes, identify the irreversible process :

    Text Solution

    |

  3. If bond energy of H(2),F(2) and HF are in the ratio 2:1:3 and DeltaH(a...

    Text Solution

    |

  4. One mole of non- ideal gas undergoes a change of state (1.0 atm, 3.0L,...

    Text Solution

    |

  5. Calculate the final pressure of a sample of carbon dioxide that expand...

    Text Solution

    |

  6. The heat evolved from the combustion of carbon is used to heat water. ...

    Text Solution

    |

  7. The equilibrium constant for A(g)+B(2)(g) hArr AB(2)(g)" "k(p)=1...

    Text Solution

    |

  8. When 1L of NaOH(1M) is mixed with 1L of HCl(1M) the temperature of rea...

    Text Solution

    |

  9. 2Fe+(3)/(2)O(2)rarr Fe(2)O(3)" "xkJ//mol e 2Fe+O(2) rarr 2FeO" ...

    Text Solution

    |

  10. The species which by definition has zero standard molar enthaly of for...

    Text Solution

    |

  11. In which of the following changes at constant pressure, is work done b...

    Text Solution

    |

  12. One gram of an organic liquid X ( molecular mass 78) liberates 160J of...

    Text Solution

    |

  13. Bond energies are equal to dissociation energies in case of :

    Text Solution

    |

  14. S( rhombic ) + O(2) rarr SO(2)," " DeltaH=-297.5kJ S( monoclini...

    Text Solution

    |

  15. A system absorbs 300cal of heat , its volume doubles and temperature r...

    Text Solution

    |

  16. In which of the following changes , DeltaH^(@) is always negative :

    Text Solution

    |

  17. Calculate the enthalpy change when 50 mL of 0.01 M Ca(OH)(2) reacts wi...

    Text Solution

    |

  18. Calculate difference between DeltaH and DeltaU when 1 mole of grey tin...

    Text Solution

    |

  19. Temperature of 1mol of a gas is increased by 1^(@) at constant pressur...

    Text Solution

    |

  20. A sample of oxygen gas expands its volume from 3L to 5L against a cons...

    Text Solution

    |