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Na- amalgam is prepared by electrolysis ...

`Na-` amalgam is prepared by electrolysis of `NaCl` solution using liquid `Hg` as cathode . How long should the current of `10 amp`. Is passed to produce `10% Na-Hg` on a cathode of `10gm Hg`. ( atomic mass of `Na=23)`.

A

`7.77 `min

B

`9.44` min.

C

`5.24 mi n.`

D

`11.39 mi n`.

Text Solution

Verified by Experts

The correct Answer is:
1

90 gm Hg has 10 gm Na
10 gm Hg `=(10)/(90)xx10=(10)/(9)gm" "Na`
weight of Na`=(M)/(n)xx(ixxt)/(96500)`
`(10)/(9)=(23)/(1)xx(10xxt)/(96500)" "[:.Na^(+)+erarrNa]`
`t=(10xx96500)/(9xx10xx23)=7.77mi n`
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