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In an ionic solid r((+))=1.6A and r((-))...

In an ionic solid `r_((+))=1.6A` and `r_((-))=1.864A`. Use the radius ratio to determine the edge length of the cubic unit cell in `A`.

A

4

B

`2sqrt(3)`

C

`3sqrt(3)`

D

`(4)/(sqrt(3))`

Text Solution

Verified by Experts

The correct Answer is:
1

`(r_(+))/(r_(_))=(1.6)/(1.864)=0.858`
So, it is `CsCl` type of unit cell
So `sqrt(3)a=2(r_(+)+r_(_))`
So, `a=(2(1.864+1.6))/(sqrt(3))Å=2xx2Å=4Å`
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