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One mole of complex compound Co(NH3)5Cl3...

One mole of complex compound `Co(NH_3)_5Cl_3` gives 3 moles of ions on dissolution in water. One mole of same complex reacts with two moles of `AgNO_3` to yield two moles of `AgCl(s)`. The complex is:

A

`[Cr(H_(2)O)_(5)Cl]Cl_(2).H_(2)O`

B

`[Co(NH_(3))_(6)]Cl_(3)`

C

`[Cr(H_(2)O_(3))_(4)Cl_(2)`

D

`[Cr(H_(2)O)_(6)]Cl_(3)`

Text Solution

Verified by Experts

The correct Answer is:
4

`[Cr(H_(2)O)_(6)]Cl_(3)overset(Ar)(hArr)[Cr(H_(2)O)_(6)]^(3+)+3Cl^(-)`
So, total number of ions `1+3=4`
`{:(,Cl^(-),+,Ag^(+),rarr,AgCldarr("while")),( :." ","one mole",,"one mole","one mole"),( :." ","three mole",,"three mole","three mole"):}`
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