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Anhydroug A Cl(3) is covalent . From the...

Anhydroug `A Cl_(3)` is covalent . From the data given below
Lattice Energy `=5137KJ//mol`
`DeltaH` hydrogen for `Al^(3+)=-4665KJ//mol`
`DeltaH` hydration for `Cl^(-)=-381KJ//mol`
Identify the correct statement.

A

It will remain covalent in aqueous solution

B

The solution will consist of `Al^(3+) & Cl^(-)`

C

The solution will consist of hydrated `Al^(3+) & Cl^(-)`

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
3


`implies" "DeltaH_("solution")=-4665-3xx381+5137lt0`
Hence `AlCl_(3)` will dissolve and solution consists of hydrated `Al^(3+)` and `Cl^(-)` ions.
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Ionisation energy of A1=5137KJmol^(-1)(DeltaH) hydration of Al^(3+)=-4665KJmol^(-1).(DeltaH)_(hydration) for Cl^(-)=-381KJmol^(-1) . Which of the following statement is correct?

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