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Arrange the following compounds in incre...

Arrange the following compounds in increasing order of their ionic character `:`
`SnC_(2),SnCl_(4),SiCl_(4),SnF_(4),SnF_(2)`

A

`SnF_(2) lt SnCl_(2) lt SnF_(4) lt SnCl_(4),SiCl_(4)`

B

`SnF_(2) lt SnCl_(2) lt SnF_(4) lt SiCl_(4) lt SnCl_(4)`

C

`SiCl_(4) lt SnCl_(4) lt SnF_(4) lt SnCl_(2) lt SnF_(2)`

D

`SnCl_(4) lt SnF_(4) lt SnCl_(2) lt SnF_(2) lt SiCl_(4)`

Text Solution

Verified by Experts

The correct Answer is:
3

As the size o fthe cations increases in the order , `Si^(4+) lt Sn^(4+) lt Sn^(2+)`
and for size of anions , `F^(-) lt Cl^(-)`
so the order of increasing ionic character is `, SiCl_(4) lt SnCl_(4) lt SnF_(4) lt SnCl_(2) lt SnF_(2)`
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