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Which of the following statements is (ar...

Which of the following statements is (are) correct ?

A

The hydrides of group `15` elements act as oxidising agents

B

The hydrides of group `15` elements act as reducing agents

C

The oxidising power increases in going from `NH_(3)` "to" `BiH_(3)`

D

The reduciing power increases in going from `NH_(3)` "to" `BiH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
BD

All acts as reducing agent and the increasing order of reducing character is `NH_(3) lt PH_(3) lt AsH_(3) lt BiH_(3)` on account of decreasing M-H bond dissociation energies with increasing size of central atoms. `NH_(3)` only a mild reducing agent.
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