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The pH of solution, containing 0.1N HCl ...

The `pH` of solution, containing `0.1N` HCl and `0.1N` `CH_(3)COOH(K_(a)=2xx10^(-5))` is

A

1

B

`0.7`

C

`2`

D

`1.3`

Text Solution

AI Generated Solution

The correct Answer is:
To find the pH of a solution containing 0.1N HCl and 0.1N acetic acid (CH₃COOH), we can follow these steps: ### Step 1: Understand the Contributions to pH HCl is a strong acid and dissociates completely in solution, while acetic acid (CH₃COOH) is a weak acid and does not dissociate completely. Therefore, the pH of the solution will primarily be determined by the HCl concentration. ### Step 2: Calculate the Contribution of HCl Since HCl is a strong acid, its concentration of hydrogen ions [H⁺] will be equal to its normality: \[ [H^+] = 0.1 \, \text{N} \, \text{(from HCl)} \] ### Step 3: Calculate the pH from H⁺ Concentration The pH is calculated using the formula: \[ \text{pH} = -\log[H^+] \] Substituting the value of [H⁺]: \[ \text{pH} = -\log(0.1) \] ### Step 4: Simplify the Logarithm We can express 0.1 as \( 10^{-1} \): \[ \text{pH} = -\log(10^{-1}) \] Using the property of logarithms, this simplifies to: \[ \text{pH} = 1 \] ### Step 5: Consider the Contribution from Acetic Acid The dissociation constant \( K_a \) for acetic acid is given as \( 2 \times 10^{-5} \). However, since HCl is a strong acid and will dominate the pH, the contribution from acetic acid can be neglected. ### Final Answer Thus, the pH of the solution is: \[ \text{pH} = 1 \]

To find the pH of a solution containing 0.1N HCl and 0.1N acetic acid (CH₃COOH), we can follow these steps: ### Step 1: Understand the Contributions to pH HCl is a strong acid and dissociates completely in solution, while acetic acid (CH₃COOH) is a weak acid and does not dissociate completely. Therefore, the pH of the solution will primarily be determined by the HCl concentration. ### Step 2: Calculate the Contribution of HCl Since HCl is a strong acid, its concentration of hydrogen ions [H⁺] will be equal to its normality: \[ [H^+] = 0.1 \, \text{N} \, \text{(from HCl)} \] ...
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