Home
Class 12
CHEMISTRY
Calculate pressure (in atm) of a Vander-...

Calculate pressure (in atm) of a Vander-waal gas taken at temperature of 399K if its density is equal to `12gm//L`. Given : `a= 6.4 atm-litre^2 mol^(-2)` and `b=0.01 L mol^(-1)` molar mass = 48, R=0.0821 `atm-L mol^(-1) K^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
8

`(P-a/(V_(m^(2))))(V_(m)-b)=RT " " d=M/V`
`(P-6.4/42)(4-0.01)0.0821 xx 399 " " 12=48/V`
`P=781 atm " " V=4L`
Promotional Banner

Topper's Solved these Questions

Similar Questions

Explore conceptually related problems

Pressure exerted by 1 mole of methane in a 0.25 litre container at 300K using Vander Waal’s equation : (Given : a = 2.253 "atm" l^(2) "mol"^(-2) and b = 0.0428 l "mol"^(-1) ) is

The volume of 2.8g of CO at 27^(@)C and 0.821 atm pressure is (R=0.0821 lit. atm mol^(-1)K^(-1))

Calculate the pressure exerted by 16 g of methane in a 250 mL container at 300 K using van der Waal's equation. What pressure will be predicted by ideal gas equation ? a = 2.253 atm L^(2) mol^(-2), b = 0.0428 L mol^(-1) R = 0.0821 L atm K^(-1) mol^(-1)

Pressure exerted by 1 mole of methane, in a 0.25 litre container at 300K using van der Waals' equation (given a= 2.253 atm L^(2) mol^(-2), b= 0.0428L mol^(-)) is

Assuming CO_(2) to be van der Waals gas, calculate its Boyle temperature. Given a=3.59" L"^(2)" atm " mol^(-2) and b=0.0427" L "mol^(-1) .

What is the compressibility factor (Z) for 0.02 mole of a van der Waals's gas at pressure of 0.1 atm. Assume the size of gas molecules is negligible. Given : RT=20 L atm mol^(-1) and a=1000 atm L^(2) mol^(-2)

Calculate the critical constants of a gas whose van der Waals constants are : a=0.751" L"^(2)" atm "mol^(-2) and b=0.0226" L mol"^(-1) .

Calculate the pressure excerted by 5 mol of CO_(2) in 1 L vessel at 47^(@)C using van der Waals equation. Also report the pressure of gas if it behaves ideally in nature. (a=3.592 atm L^(2) mol^(-2), b=0.0427 L mol^(-1))

Find the temperature at which 3 moles of SO_(2) will occupy a volume of 10 litre at a pressure of 15 atm a = 6.71 atm "litre"^(2) mol^(-2), b = 0.0564 " litre " mol^(-1)

BANSAL-TEST PAPERS-CHEMISTRY
  1. Which of the following compounds act as Lewis acid as well as Lewis ba...

    Text Solution

    |

  2. Which compounds are more basic than

    Text Solution

    |

  3. Calculate pressure (in atm) of a Vander-waal gas taken at temperature ...

    Text Solution

    |

  4. Find the total number of P-S-P linkages in P(4)S(10) ?

    Text Solution

    |

  5. Consider given compounds & write the number of compounds which have hi...

    Text Solution

    |

  6. According to Maxwell's theory of electron dynamics, an electron going ...

    Text Solution

    |

  7. How many compounds are chain, positional or functional group isomer of...

    Text Solution

    |

  8. An excited hydrogen atom emits a photon of wavelength lambda in return...

    Text Solution

    |

  9. Which of the following has monoatomic anion in the solid state?

    Text Solution

    |

  10. Indentify strongest acid amongst followings.

    Text Solution

    |

  11. 10 ml of ethane gas is mixed with 40ml oxygen gas in an eudiometer tub...

    Text Solution

    |

  12. The correct order of thermal stability is

    Text Solution

    |

  13. What is correct IUPAC name of

    Text Solution

    |

  14. As per KTG, molecules in gaseous state are under continuous motion wit...

    Text Solution

    |

  15. As per KTG, molecules in gaseous state are under continuous motion wit...

    Text Solution

    |

  16. As per KTG, molecules in gaseous state are under continuous motion wit...

    Text Solution

    |

  17. When photons of energy 4.25eV strike the surface of a metal A, the eje...

    Text Solution

    |

  18. Which compounds have high boiling point in comparision to

    Text Solution

    |

  19. Select the correct statement regarding XeF2

    Text Solution

    |

  20. Which option(s) is/are incorrect.

    Text Solution

    |