Home
Class 12
CHEMISTRY
72.5g of phenol is dissolved in 1 kg of ...

72.5g of phenol is dissolved in 1 kg of a solvent `(K_(f)=14)` which leads to dimerization of phenol and freezinfg point is lowered by 7 kelvin. What percentage of toal phenol is present in dimeric form?

Text Solution

Verified by Experts

The correct Answer is:
35% phenol is present in demeric form

`DeltaT_(b)=[1+((1)/(2)-1)alpha]xxK_(b)xx(W_("solute")xx1000)/(m_("solute")xxW_("solvent"))` lt brgt `7=[1+((1)/(2)-1)alpha]xx(14xx72.5xx1000)/(94xx1000)`
`a=0.704`
`~~70%`
`therefore`35% Phenol is present in diermic form.
Promotional Banner

Topper's Solved these Questions

Similar Questions

Explore conceptually related problems

72.5g of phenol is dissolved in 1kg of a solvent (k_(f) = 14) which leads to dimerization of phenol and freezing point is lowered by 7 kelvin. What percent of total phenol is present in dimeric form?

In an experiment, 72.5 g of C_(6)H_(5)OH (phenol) is dissolved in a solvent of K_(f)=14 . If the depression in freezing point is 7 K , find the percentage of phenol that dimerizes.

1575.2 g of C_(6)H_(5)OH (phenol) is dissolved in 960 g of a solvent of solvent of K_(f)=14 K kg mol^(-1) . If the depression in freezing point is 7 K , then find the percentage of phenol that dimerizes.

75.2 g of C_(6)H_(5)OH (phenol) is dissolved in a solvent of K_(f) = 14 . If the depression in freezing point is 7K , then find the percentage of phenol that dimerises.

75.2 g of C_(6)H_(5)OH (phenol) is dissolved in 1 kg of solvent of k_(f)= 14 K "molality"^(-1) . If depression in freezing point is 7 K . Calculate % of phenol that dimerises.

A hypothetical solute AB is 50% dissociated at freezing point and 80% dissociated at boiling point of solution.If 2 mole of solute is dissolved in 500 g solvent and the difference in boiling point and freezing point of solvent is 100K then calculate the difference in boiling point and freezing point of solution. [Given K_(b)= 0.5Kkgmol^(-1) K_(f)=2.0Kkgmol^(-1) ]

0.48 g of a substance is dissolved in 10.6 g of C_(6)H_(6) .The freezing point of benzene is lowered by 108^(@)C . What will be the mol.wt. of the ( K_(f) for benzene = 5 )

BANSAL-SOLUTIONS-Exercise4
  1. 1.22 g of benzoic acid is dissolved in (i) 100g acetone (K(b) for acet...

    Text Solution

    |

  2. The elevation in boiling point, when 13.44g of freshly prepared CuCl(2...

    Text Solution

    |

  3. 72.5g of phenol is dissolved in 1 kg of a solvent (K(f)=14) which lead...

    Text Solution

    |

  4. When 20g of naphtholic acid (C(11)H(8)O(2)) is dissolved in 50 g of be...

    Text Solution

    |

  5. Properties such as boiling point, freezing point and vapour pressure o...

    Text Solution

    |

  6. Properties such as boiling point, freezing point and vapour pressure o...

    Text Solution

    |

  7. Properties such as boiling point, freezing point and vapour pressure o...

    Text Solution

    |

  8. The Henry's law constant fo the solubility of N(2) gas in water at 29...

    Text Solution

    |

  9. The freezing point ("in"^(@)"C") of a solution containing 0.1 g of K(3...

    Text Solution

    |

  10. For a dilute solution containing 2.5 g of a non-volatile non-electroly...

    Text Solution

    |

  11. Benzene and naphthalene from an ideal solution at room temperature. Fo...

    Text Solution

    |

  12. MX(2) dissociates into M^(2+) and X^(ө) ion in an aqueous solution, wi...

    Text Solution

    |

  13. If the freezing point of a 0.01 molal aqueous solution of a cobalt (II...

    Text Solution

    |

  14. At 80^(@)"C", the vapour pressure of pure liquid 'A' is 250 mm Hg and...

    Text Solution

    |

  15. The vapour pressure of water at 20^(@) is 17.5 mmHg. If 18 g of glucos...

    Text Solution

    |

  16. Two liquids X and Y from an ideal solution at300K, Vapour pressure of ...

    Text Solution

    |

  17. A binary liquid solution is prepared by mixing n-heptane and ethanol. ...

    Text Solution

    |

  18. If sodium sulphate is considered to be completely dissociated into cat...

    Text Solution

    |

  19. On mixing, heptane and octane form an ideal solution. At 373K the vapo...

    Text Solution

    |

  20. Ethylene glycol is used as an antifreeze in a cold climate. Mass of et...

    Text Solution

    |