Home
Class 12
CHEMISTRY
In a solid, atom M occupies ccp lattice ...

In a solid, atom M occupies ccp lattice and 1/3rd of tetrahedral voids are occupied by atom N. Find the formula of solid formed by M and N-

A

`M_(3)N_(2)`

B

`M_(2)N_(3)`

C

`M_(4)N_(3)`

D

`M_(3)N_(4)`

Text Solution

Verified by Experts

The correct Answer is:
A

Suppose in the solid number of M atoms = n
So the number of tetrahedral voids = 2n
`therefore` Number of N atoms = `1/3(2n)`
Therefore, ratio of M : M = `n:2/3n=3:2`, i.e., formula of the solid is `M_(3)N_(2)`
Promotional Banner

Topper's Solved these Questions

  • SOLID STATE

    CHHAYA PUBLICATION|Exercise SOLVED NCERT EXEMPLAR PROBLEMS|53 Videos
  • SOLID STATE

    CHHAYA PUBLICATION|Exercise SHORT ANSWER TYPE|10 Videos
  • SOLID STATE

    CHHAYA PUBLICATION|Exercise ADVANCED LEVEL NUMERICAL BANK|17 Videos
  • PREVIOUS YEARS QUESTION PAPER 2019

    CHHAYA PUBLICATION|Exercise WBCHSE 2019 PART-B|19 Videos
  • SOME p-BLOCK ELEMENTS

    CHHAYA PUBLICATION|Exercise PRACTIVE SET 11|15 Videos

Similar Questions

Explore conceptually related problems

A forms hcp lattice and B are occupying 1/3rd of tetrahedral voids, then the formula of compound is-

A forms hcp lattice and B are occupying 1/3rd of tetrahedral voids, then the formula of compound is-

In a compound, nitrogen atoms (N) make cubic close packed lattice and metal atoms (M) occupy one-third of the tetrahedral voids present. Determine the formula of the compound formed by M and N?

Structure of a mixed oxide is cubic close-packed (ccp). The cubic unit cell of mixed oxide is composed of oxide ions. One-fourth of the tetrahedral voids are occupied by divalent metal A and the octahedral voids are occupied by a monovalent metal B. The formula of the oxide is-

Atoms of elements B from hep lattice and those of element A occupy two-thirds of tetrahedral voids. What is the formula of the compound formed by elements A and B ?

A crystalline compound consists of elements A and B. Atoms of element B from the cubic close-packed structure, in which half of the tetrahedral voids are occupied by A atoms. Determine the empirical formula of the compound.

A compound formed by two elements M and N . Element N forms ccp and atoms of M occupy 1//3rd of tetrahedral voids. What is the formula of th compound?

A compound is formed by two elements, M and N. N forms ccp & atoms of M occupy 1/3 rd of tetrahedral voids. What is the formula of the compound?

In a crystalline solid , anion B^- are arranged in a cubic close packing. Cations A^+ are equally distributed between octahedral and tetrahedral voids. If all the octahedral voids are occupied, what is the formula of the solids?

In a cubic close packed structure (ccp) of mixed oxides, it is found that lattice has O^(2-) ions and one half of the octahedral voids are occupied by trivalent cations (A^(3+)) and one-eighth of the tetrahedral voids are occupied by divalent cations (B^(2+)) . Derive the formula of the mixed oxide.

CHHAYA PUBLICATION-SOLID STATE-ENTRANCE QUESTION BANK
  1. In calcium fluoride, having the fluorite structure, the coordination n...

    Text Solution

    |

  2. The ionic radii of A^(+)andB^(-) ions are 0.98xx10^(-10)m and 1.81xx10...

    Text Solution

    |

  3. Lithium has bcc structure. Its density is 530kg*m^(-3) and its atomic ...

    Text Solution

    |

  4. Which is the incorrect statement-

    Text Solution

    |

  5. Iron exhibits bcc structure at room temperature. Above 900^(@)C, it tr...

    Text Solution

    |

  6. Schottky defect is-

    Text Solution

    |

  7. CsCl has bcc arrangement. Its unit cell edge length is 400 pm. Its int...

    Text Solution

    |

  8. If Si is doped with B-

    Text Solution

    |

  9. In bcc structure contribution of corner and central atom is-

    Text Solution

    |

  10. In a solid, atom M occupies ccp lattice and 1/3rd of tetrahedral voids...

    Text Solution

    |

  11. A forms hcp lattice and B are occupying 1/3rd of tetrahedral voids, th...

    Text Solution

    |

  12. Ca^(2+)andF^(-) are located in CaF(2) crystal, respectively at face-ce...

    Text Solution

    |

  13. Addition of group-13 elements to intrinsic semiconductors result in-

    Text Solution

    |

  14. The yellow colour in NaCl crystals is due to-

    Text Solution

    |

  15. Which of the following is an amorphous solid-

    Text Solution

    |

  16. If an atom crystallises in bcc lattice with r = 4Å then the edge lengt...

    Text Solution

    |

  17. ZnO is white when cold and yellow when heated. It is due to the develo...

    Text Solution

    |

  18. A forms hcp lattice and B are occupying 1/3rd of tetrahedral voids, th...

    Text Solution

    |

  19. F-centre is-

    Text Solution

    |

  20. What colour is observed when ZnO is heated-

    Text Solution

    |