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Calculate the energy emitted when electr...

Calculate the energy emitted when electron of 1.0g atom of hydrogen undergo transition emitting the spectral line of lowest energy in the visible region of its atomic spectrum `[R_(H)=1.1xx10^(7)m^(-1)`]

Text Solution

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The given spectral line in the visible region, corresponds to the Balmer series, for Balmer series, `overline(v)=R_(H)[(1)/(n_(1)^(2))-(1)/(n_(2)^(2))]`
For lowest energy, `n_(1)=2 and n_(2)=3`.
`therefore (1)/(lamda)=R_(H)[(1)/(2^(2))-(1)/(3^(2))]=1.1xx10^(7)xx(5)/(36)`
the amount of energy emitted during the transition of an electron, `E=hv=hxx(c)/(lamda)=hxxcxx(1)/(lamda)`
`=6.626xx10^(-34)xx3xx10^(8)xx(1.1xx10^(7)xx(5)/(36))=3.037xx10^(-19)J`
`therefore`The energy emitted when electrons of 1gram-atom of hydrogen undergo transition`=N_(0)xxhv`
`=6.022xx10^(23)xx(3.037xx10^(-19))J=18.28xx10^(4)J=182.8kJ`.
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