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The energy required to break one mole of...

The energy required to break one mole of hydrogen-hydrogen bonds in `H_(2)` is 436 kJ. What is the longest wavelength of light required to break a single hydrogen-hydrogen bond-

A

68.5 nm

B

137 nm

C

274 nm

D

548 nm

Text Solution

Verified by Experts

The correct Answer is:
C

The energy required to break a H-H bond
`=(436xx10^(3))/(6.022xx10^(23))J`
Therefore, from the equation, `E=(hc)/(lamda)`
we get, `(hc)/(lamda)=(436xx10^(3))/(6.022xx10^(23)`
`therefore lamda=(6.022xx10^(23))/(436xx10^(3))xxhc`
`=(6.022xx10^(23))/(436xx10^(3))xx6.626xx10^(-34)xx3xx10^(8)`
`=2.74xx10^(-7)m=274nm`
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