Give the hybridisation of P and PC l(5) ...

Give the hybridisation of P and `PC l_(5) `. Why are axial bonds longer as compared to equatorial bonds?

Text Solution

Verified by Experts

`sp^(3)d`. This is due to greater repulsion on the axial bond pairs bythe equatorial bonds pairs.

Topper's Solved these Questions

CHEMICAL BONDING AND MOLECULAR STRUCTURE
CHHAYA PUBLICATION|Exercise SOLVED WBCHSE SCANNER|40 Videos
CHEMICAL BONDING AND MOLECULAR STRUCTURE
CHHAYA PUBLICATION|Exercise SOLVED NCERT EXERCISE|32 Videos
CHEMICAL BONDING AND MOLECULAR STRUCTURE
CHHAYA PUBLICATION|Exercise WARM UP EXERCISE|106 Videos
CLASSIFICATION OF ELEMENTS & PERIODICITY IN PROPERTIES
CHHAYA PUBLICATION|Exercise PRACTICE SET|12 Videos

Similar Questions

Explore conceptually related problems

Describe the hybridisation in case of PCl_5 . Why are the axial bonds longer as compared to equatorial bonds?

Describe the hybridisation in case of PCl_(5) . Why are the axiial bonds longer as compared to equatorial bonds?

Describe hybridisation in the case of PCl_(5) and SF_(6) The axial bonds are longer as compared to equatorial bonds in PCl_(5) whereas in SF_(6) both axial bonds and equatorial bonds and have the same bond length. Explain.

Explain why the axial bonds in PC l_(5) are longer than the equatorial bonds.

Why are the pi -bonds weaker and more reactive than the sigma -bonds?

Why is a coordinate bond referred to as a semipolar bond?

sp^(3) hybridisation is involved in CH_(4), H_(2)O and NH_(3) . Why are the bond angles different in three cases?

Give the states of hybridisation of central atoms of PC l_(4)^(+)&XeOF_(4) ?

In both water and dimethyl ether (CH_(3)-underset(* *)overset(* *)O-CH_(3)), oxygen atom is central atom, and has the same hybridisation, yet they have different bond angles. Which one has greater bond angle ? Give reason.

Why are the P-Cl bonds in PC l_(5) not of same length?

CHHAYA PUBLICATION-CHEMICAL BONDING AND MOLECULAR STRUCTURE-QUESTIONS-ANSWER ZONE FOR BOARD EXAMINATION

Give examples of an anion and a cation which are isostructural with BF...
Text Solution
|
Arrange in order of decresing size: sp,sp^(2),sp^(3)
Text Solution
|
Give the hybridisation of P and PC l(5) . Why are axial bonds longer a...
Text Solution
|
mention the change in hybridisation (if any) of the AI-atom in the rea...
Text Solution
|
Is there any change in hybridisation of B and N-atoms as a result of t...
Text Solution
|
Although the O-atoms in water and diethyl ether are sp^(3)-hybridised,...
Text Solution
|
Draw the resonance structures of N(2)O obeying the octet rule.
Text Solution
|
Which of the following hybrid orbitals possess two types of angles? ...
Text Solution
|
Which of the following are isostructural? (1) BF(3), (2) SO(4)^(2-),...
Text Solution
|
Give an example of an anion which is isostructural with BF(3).
Text Solution
|
Out of SF(6) and SC l(2), S has highe electronegativity in which of th...
Text Solution
|
Arrange in the order of increasing ionic character: C-H,F-H, Br-H, N...
Text Solution
|
What is the shape of a molecule, AB(2) if it has a definite dipole mom...
Text Solution
|
The dipole moment of HF is 2.0 D. calculate its value in coulomb-metre...
Text Solution
|
N(2)O is polar even though it is linear-why?
Text Solution
|
Arrange halobenzenes (C(6)H(5)-X,X=F,Cl.Br.I) in the order of their in...
Text Solution
|
The dipole moment of a molecule, mu=exxd. What is the value of d in ca...
Text Solution
|
Arrange the following in the order of decreasing strengths: N-H . . ....
Text Solution
|
Arrange the following interactions in the order of their increasing st...
Text Solution
|
Which of the following species has same number of unpaired electrons? ...
Text Solution
|