Home
Class 11
CHEMISTRY
Explain the following observations: (1...

Explain the following observations:
(1) `H_(2)^(+)` ion is more stable than `H_(2)^(-)` ion even though the bond orders of both the ions are the same.
(2) When a magnet is dipped in a jar containing liquid oxygen, some oxygen molecules cling to it.

Text Solution

Verified by Experts

(1) The antibonding `sigma_(1s)^(**)` molecular orbital of `H_(2)^(-)` ion contains one electron but the antibonding `sigma_(1s)^(**)` molecular orbital of `H_(2)^(+)` ion contains no electron. Therefore `H_(2)^(+)` ion is more stable than `H_(2)^(-)` ion, even though their bond order are the same.
(2) The electronic configuration of oxygen of oxygen molecule `(O_(2))` shows the presence of two unpaired electorns this suggests that the molecule is paramagnetic in nature. thus, when a bar magnet is dipped in a jar off liquid oxygen, some molecule cling to it.
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CHHAYA PUBLICATION|Exercise SOLVED WBCHSE SCANNER|40 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CHHAYA PUBLICATION|Exercise SOLVED NCERT EXERCISE|32 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CHHAYA PUBLICATION|Exercise WARM UP EXERCISE|106 Videos
  • CLASSIFICATION OF ELEMENTS & PERIODICITY IN PROPERTIES

    CHHAYA PUBLICATION|Exercise PRACTICE SET|12 Videos

Similar Questions

Explore conceptually related problems

Find out the bond order of H_2^+ ion.

Explain why Fe^(3+) is more stable than Fe^(2+) ion.

Explain the following observation: The N-O bond in NO_2^- ion is shorter in length than the N-O bon in NO_3^- ion.

State the Hund’s rule of maximum multiplicity. Wh Fe^(3+) ion is more stable than Fe^(2+) ion?

Why mercurous ion exist in Hg_2^(2+) form? Why Fe^(3+) is more stable than Fe^(2+) ?

The bond order of He_(2)^(+) ion is- (1)/(2),1,(3)/(2),O .

which among the following pairs of ions cannot be separated by H_(2)S in the presence of dilute HCl ?

Give the formula of the following coordination entities : (b) Ni^(2+) ion is bound to two water molecules and two oxalate ions. Write the name and magnetic behaviour of each of the above coordination entities.

Although H_(2),Li_(2) and B_(2) molecules have the same bond order (i.e., 1), yet they are not equally stable. Explain this observation and arrange them in order of decreasing stability.

CHHAYA PUBLICATION-CHEMICAL BONDING AND MOLECULAR STRUCTURE-QUESTIONS-ANSWER ZONE FOR BOARD EXAMINATION
  1. Which one between p and sp-orbital has more directional characteristic...

    Text Solution

    |

  2. In a certain polar solvent, PCl(5) undergoes ioonisation as follows: 2...

    Text Solution

    |

  3. MgCl(2) is linear but SnCl(2) is angular-explain.

    Text Solution

    |

  4. Arrange the following in the increasing order of their polarities and ...

    Text Solution

    |

  5. Identify the three isomeric chlorotoluenes having dipole moments: 1.35...

    Text Solution

    |

  6. Which has the least dipole moment-1 -butene, cis-2-butene, trans-2-but...

    Text Solution

    |

  7. What do you mean by hydrogen bond donor and hydrogen bond acceptor? De...

    Text Solution

    |

  8. The boiling point of water (100^(@)C) is much higher than that of HF(1...

    Text Solution

    |

  9. Explain the following observation: (1) Glycerol [HOCH(2) CH(OH)CH(2)OH...

    Text Solution

    |

  10. Arrange water, methanol and dimethyl ether in increasing order of thei...

    Text Solution

    |

  11. At equilibrium acetyl acetone (CH(3)COCH(2)COCH(3)) exists mainly (~~8...

    Text Solution

    |

  12. State the useful rule related to the solubility of a compound. Unlike...

    Text Solution

    |

  13. Inert gases do not generally participate in chemical reaction-explain ...

    Text Solution

    |

  14. The bond dissociation enthalpy of N(2) is higher than that of N(2)^(+)...

    Text Solution

    |

  15. Arrange the following species in order of their in-creasing bond lengt...

    Text Solution

    |

  16. Explain the following order of bond dissociation enthalpies: F-F lt Cl...

    Text Solution

    |

  17. Determine the shapes of the given molecules or ions: (1) POCl(3) (...

    Text Solution

    |

  18. The molecule of any compound composed of two dissimilar elements is al...

    Text Solution

    |

  19. Explain the following observations: (1) H(2)^(+) ion is more stable ...

    Text Solution

    |

  20. It is correct to say that bond order always increases with loss of ele...

    Text Solution

    |