Comment on the validity of Boyle's law f...

Comment on the validity of Boyle's law for the following reaction: `N_(2)O_(4)(g)hArr 2NO_(2)(g)`.

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The number of molecules of `N_(2)O_(4) and NO_(2)` vary with the pressure at constant temperature. Hence, mass of the gas mixture does not remain constant. Thus, boyle's law is not applicable here.

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