Home
Class 11
CHEMISTRY
Derive van der waals equation for 'n' mo...

Derive van der waals equation for 'n' mol of a real gas from the equation for 1 mol of the gas.

Text Solution

Verified by Experts

van der waals equation for 1 mol of a real gas is given by-
`(P+(a)/(v^(2)))(v-b)=RT` . . [1]
If at a pressure P and a temperature T, the volume of 'n' moles of this gas be V, then `v=(V)/(n)`. Putting `v=(V)/(n)` in equation [1], we have
`(P+(a)/(((V)/(n))^(2)))((V)/(n)-b)=RT or (P+(n^(2)a)/(V^(2)))(V-nb)=nRT`
This is the van der waals equation for 'n' mol of real gas.
Promotional Banner

Topper's Solved these Questions

  • STATES OF MATTER : GASES AND LIQUIDS

    CHHAYA PUBLICATION|Exercise SOLVED WBCHSE SCANNER|23 Videos
  • STATES OF MATTER : GASES AND LIQUIDS

    CHHAYA PUBLICATION|Exercise SOLVED NCERT EXERCISE|23 Videos
  • STATES OF MATTER : GASES AND LIQUIDS

    CHHAYA PUBLICATION|Exercise WARM UP EXERCISE|104 Videos
  • SOME BASIC CONCEPTS OF CHEMISTRY

    CHHAYA PUBLICATION|Exercise PRACTICE SET|13 Videos
  • STRUCTURE OF ATOM

    CHHAYA PUBLICATION|Exercise PRACTICE SET|15 Videos

Similar Questions

Explore conceptually related problems

Write the van der Waals equation for 5 mole of ideal gas.

Write the Vander Walls equation for n'mole of the real gas.

Write down the van der Waals' equation for n moles of real gas .

Write van der Waals equation for 1 mol real gas and deduce the equation for the gas containing n molecules from it.

(i) Write down van der waals equation for 1 mol of a gas and hence deduce the equation for the same for n mol of the gas. (ii) Arrange CO_(2),SO_(2) and NO_(2) gases in increasing order of their rates of diffusion iunder the same condition of temperature and pressure wil reason.

Write ideal gas equation for 1mole of gas.

Write the van der Waals equation for real gas ? Write the unit of a and b.

Write the van der wals equation for a real gas containig n molecules.

In the van der waals equation, 'a' signifies-

CHHAYA PUBLICATION-STATES OF MATTER : GASES AND LIQUIDS-QUESTION-ANSWER ZONE FOR BOARD EXAMINATION
  1. Under similar conditions of temperature and pressures, if the time tak...

    Text Solution

    |

  2. Molar mass of UF(6) is 176 times as high as that of H(2), yet at a par...

    Text Solution

    |

  3. If, at a given temperature, the totla kinetic energy of the molecules ...

    Text Solution

    |

  4. For the molecules of a given gas at a constant temperature, arrange th...

    Text Solution

    |

  5. A and B are closed flasks having the same volume. In flask A, O(2) gas...

    Text Solution

    |

  6. Which one of the gases, under the given conditions, exhibits reas gas ...

    Text Solution

    |

  7. Under what condition can a gas be liquefied? (1) T=T(c) and P lt P(c...

    Text Solution

    |

  8. Two gases, obeying van der waals equation, have identical values of 'b...

    Text Solution

    |

  9. A real gas follows van der waals equation. Find the compressibility fo...

    Text Solution

    |

  10. Derive van der waals equation for 'n' mol of a real gas from the equat...

    Text Solution

    |

  11. Write the van der wals equation for a real gas containig n molecules.

    Text Solution

    |

  12. What will the nature of PV vs P graph be for a real gas at Boyle tempe...

    Text Solution

    |

  13. What will the value of compressibility factor (Z) be for a gas if the ...

    Text Solution

    |

  14. The vlaue of van der waals constant 'a' for nitrogen gas is 1.37L^(2)*...

    Text Solution

    |

  15. The values of 'a' & 'b' for three real gases A, B & C are- (a) Wh...

    Text Solution

    |

  16. Why is the potential energy of a molecule in the bulk of a liquid lowe...

    Text Solution

    |

  17. Between methanol (CH(3)OH) and water (H(2)O) whose surface tension is ...

    Text Solution

    |

  18. A liquid has a high normal boiling point. Will its viscosity and surfa...

    Text Solution

    |

  19. How is the vapour pressure of a liquid affected if the surface area of...

    Text Solution

    |

  20. Compare the viscoaity coefficient of the following liquids at a partic...

    Text Solution

    |