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[Fe^(II)Cl(CN)(4)(O(2))]^(4-) is named a...

`[Fe^(II)Cl(CN)_(4)(O_(2))]^(4-)` is named as :

A

Chloridotetracyanidodioxidoferrate (II) ion

B

chloridotetracyanidoperoxidoferrate (II) ion

C

chloridotetracyanidosuperoxidoferrate (II) ion

D

None is correct

Text Solution

Verified by Experts

The correct Answer is:
C
`[overset(+2)(Fe)overset(-1)Cloverset(-4)(CN)_(4)overset(-1)(O_(2))]^(4-)`
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In the cystal field of the complex [Fe(Cl)(CN)_(4)(O_(2))]^(4-) the electronic configuration of metalis found to be t_(2g)^(6),e_(g)^(o) then which of the following is/are true about this complex ion :

(a) Write the IUPAC name of K_3[Fe(CN)_(5)NO] [Fe(CN)_6]^(4-) is diamgnetic . Explain.

Increasing order EAN of the metals in [Ni(CN)_(4)]^(2-) (II) [Fe(CN)_(6)]^(3-) (III) [Cu(CN)_(4)]^(3-) is .

Assertion: K_(4)[Fe(CN_(6)] is diamagnetic and [Fe(H_(2)O)_(6)]Cl_(3) is paramagnetic. Reason: Hybridisation of central metal in K_(4)[Fe(CN)_(6)]" is "sp^(3) d^(2) , which in [Fe(H_(2)O)_(6)]Cl_(3)" is "d^(2) sp^(3) .

Write oxidation state and coordination number of [Co(NH_(3))_(4)Cl_(2)]^(+) ion. Calculate EAN of iron in [Fe(CN)_(6)]^(4-) . Write the IUPAC name of [Zn(NH_(3))_(4)]^(2+)

Name of following coordinatin entities and describe their structures : (i) [Fe(CN)_(6)]^(4-) (ii) [Cr(NH_(3))_(4)Cl_(2)]^(+) (iii) [Ni(CN)_(4)]^(2-) [Atomic number Fe = 26 , Cr = 24 , Ni = 28]

GRB PUBLICATION-COORDINATION COMPOUNDS-B.Nomenclature of Coordination Compounds
  1. A complex anion is formed by Osmium ( in some oxidation state ) with l...

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  2. IUPAC name of K(3)[Fe(CN)(6)] is

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  3. The IUPAC name for the complex [Co(NO(2))(NH(3))(5)]Cl(2) is :

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  4. Complex ion [FeN(3)(O(2))(SCN)(4)]^(4-) is named as : (coordination nu...

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  5. Trioxalato aluminate (III) and tetrafluoro-borate (III) ions are:

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  6. The IUPAC name of [Ni(NH(3))(4)][NiCl(4)] is :

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  7. The correct IUPAC name of [Co(CH(3)NH(2))(4)(CN)(2)]Cl:

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  8. Which option is True (T) and False (F) for IUPAC name of K(3)[Fe(CN)(6...

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  9. The IUPAC name for the coordination compound Ba[BF(4)](2) is :

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  10. The IUPAC name of the complex compound [CoCl(2)(en)(2)]Cl is :

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  11. The appropriate formula of dichloridobis(ethane-1, 2-diamine)platinum...

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  12. [Fe^(II)Cl(CN)(4)(O(2))]^(4-) is named as :

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  13. select the cottect IUPAC name of [Co(H(2)NCH(2)CH(2)NH(2))(3)](2)(SO(4...

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  14. Write the correct formula of the following complex : [Iron (III)-hexac...

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  15. Which of the following IUPAC names are incorrectly matched ?

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  16. Identify the incorrect combination of IUPAC name of the complex and it...

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  17. The correct IUPAC name of [Pt(NH(3))(2)Cl(2)] is

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  18. IUPAC name of [Pt(NH(3))(2)Cl(NO(2))] is

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  19. Correct IUPAC name of given complex :

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  20. 1 mole of which complex produces minimum number of K^(+) ions on disso...

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