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select the cottect IUPAC name of [Co(H(2...

select the cottect IUPAC name of `[Co(H_(2)NCH_(2)CH_(2)NH_(2))_(3)]_(2)(SO_(4))_(3)` is :

A

Tris (ethane-1, 2-diamine) cobalt (III) sulphate

B

Tris (ethane-1, 2-diamine) cobaltate (III) sulphate

C

Tris (ethane-1, 2-diamine) cobaltate (II) sulphate

D

None of the above

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The correct Answer is:
To find the correct IUPAC name of the complex `[Co(H2NCH2CH2NH2)3]2(SO4)3`, we will follow a systematic approach to nomenclature. ### Step-by-Step Solution: 1. **Identify the Components of the Complex:** - The complex consists of a cation and an anion. The cation is `[Co(H2NCH2CH2NH2)3]2+` and the anion is `(SO4)3-`. 2. **Determine the Anion Name:** - The anion is sulfate, which corresponds to the formula `SO4^2-`. 3. **Calculate the Charge of the Cation:** - There are three sulfate ions, each with a charge of `-2`, giving a total charge of `-6` from the anions. - Since the complex is neutral overall, the total charge of the cation must be `+6`. - The cation is `[Co(H2NCH2CH2NH2)3]`, and since there are two of these cations (as indicated by the subscript 2), the charge on one cation must be `+3`. 4. **Identify the Ligand:** - The ligand present is ethylenediamine, which can also be written as ethane-1,2-diamine. It is a bidentate ligand (it can form two bonds with the central metal). 5. **Count the Ligands:** - There are three ethylenediamine ligands in the complex, so we will use the prefix "tris" to indicate this. 6. **Determine the Oxidation State of Cobalt:** - The oxidation state of cobalt in this complex is `+3`, as calculated earlier. 7. **Construct the Cation Name:** - The name of the cation will be constructed as follows: - Ligand name: "tris(ethane-1,2-diamine)" - Metal name: "cobalt" - Oxidation state: "(III)" - Therefore, the cation name is: `tris(ethane-1,2-diamine)cobalt(III)`. 8. **Combine Cation and Anion Names:** - The full name of the complex will be the name of the cation followed by the name of the anion. - Thus, the complete name is: `tris(ethane-1,2-diamine)cobalt(III) sulfate`. ### Final Answer: The correct IUPAC name of the complex `[Co(H2NCH2CH2NH2)3]2(SO4)3` is **tris(ethane-1,2-diamine)cobalt(III) sulfate**.
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