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The compound Na(2)IrCl(6) reacts with t...

The compound `Na_(2)IrCl_(6)` reacts with triphenylphosphine in diethyleneglycol in an atmosphere of CO to give `[IrCl(CO)(PPh_(3))_(2)]`. (Atomic number of Ir=77)
Which of the following statements is/are correct ?

A

The IUPAC name of the complex is carbonylchloridobis (triphenylphosphine) iridium(I).

B

The hybridization of the metal ion is `sp^(3)`.

C

The magnetic moment (spin only) of the complex is zero.

D

The complex shows geometrical as well as ionization isomerism.

Text Solution

Verified by Experts

The correct Answer is:
A, C
`"Hyb" to dsp^(2)`, sqr. Planar.
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